CF0004
Alcohol Togni-(PhSCF2CF2)-reagent
表单
solid
反应适用性
reaction type: C-C Bond Formation
储存温度
−20°C
应用
Alcohol Togni-(PhSCF2CF2)-reagent is an electrophilic hypervalent iodine-fluoroalkyl reagent introducing the phenylsulfanyltetrafluoroethyl fragment. A phenylsulfanyltetrafluoroethyl moiety incorporated in the substrate can be treated with tributyltin hydride and generate the corresponding fluoroalkyl radical. If the substrate lacks any olefine, it can be reduced to tetrafluoroethyl group whereas if the substrate contains an olefine in the correct spatial orientation, it can lead to an intramolecular cyclisation affording tetrafluorinated cyclic structures.
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法律信息
Product of CF Plus Chemicals.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
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商品
目前的氟烷基化工具包括Togni试剂、高价碘全氟烷基化试剂、氟烷基溴化物、硅烷类和羧酸盐类以及用于后期氟烷基化的磺酰氟类。
Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.
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