表单
liquid
反应适用性
reaction type: C-C Bond Formation
SMILES字符串
FC(F)(Br)C(F)(F)Oc1ccc(cc1)Br
InChI
1S/C8H4Br2F4O/c9-5-1-3-6(4-2-5)15-8(13,14)7(10,11)12/h1-4H
InChI key
MHPXJSIMKFXETB-UHFFFAOYSA-N
应用
4-Bromophenoxytetrafluoroethyl bromide is a fluoroalkylbromide that is a radical source of the 4-bromophenoxytetrafluoroethyl moiety. Alternatively, it can also be selectively metallated at the fluorinated carbon with Turbo Grignard reagent at low temperatures resulting in a thermally unstable anion that can act as a nucleophilic fluoroalkylation reagent towards a wide variety of electrophiles, such as aldehydes, ketones or sulfonylimines.The aromatic bromide can be further subjected to Pd-catalyzed cross-coupling reactions to build molecular complexity.
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法律信息
Product of CF Plus Chemicals.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
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