D34108
二苄胺
97%
别名:
(N-苄氨基甲基)苯, DBA, N,N-二苄基胺, N-(苯基甲基)苯甲胺, N-苄基-1-苯基甲胺, N-苄基苄胺, 二苄胺（8CI）, 联苄胺
质量水平
方案
97%
表单
liquid
折射率
n20/D 1.574 (lit.)
沸点
300 °C (lit.)
mp
−26 °C (lit.)
密度
1.026 g/mL at 25 °C (lit.)
SMILES字符串
C(NCc1ccccc1)c2ccccc2
InChI
1S/C14H15N/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14/h1-10,15H,11-12H2
InChI key
BWLUMTFWVZZZND-UHFFFAOYSA-N
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一般描述
二苄胺主要用于生产对橡胶硫化过程十分重要的橡胶促进剂。 它在叔胺的亚硝化裂解反应(nitrosative cleavage)中用作前体，有助于多种化学反应。还用作钯复合物合成的中间体。
应用
- 页岩气废水环境监测：二苄胺是页岩气废水中的有害物质之一，研究表征了其在长江上游的浓度和分布，有助于改善环境管理实践（Tang et al., 2024）。
- 有机合成的进展：研究人员在通过大体积强制无痕区域选择性钯催化C（sp（2））-H活化的新（L）-单甲基酪氨酸合成策略中使用了二苄胺，展示了其在药物化合物开发中的实用性（Illuminati et al., 2023）。
- 在晶体学中的应用：阐明了二苄基胺的晶体结构，为分子相互作用和在材料科学和药物设计中的潜在应用提供了见解（Sangeetha et al., 2023）。
- 在绿色化学中的应用：二苄胺促进三唑形成反应的绿色方法，旨在通过最大限度减少环境影响和提高反应效率来开发抗癌药物（Rastogi et al., 2023）。
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1C
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
289.4 °F - closed cup
闪点(°C)
143 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Thermal decomposition of the rubber vulcanization agent, zinc dibenzyldithiocarbamate, and its potential role in nitrosamine formation in hams processed in elastic nettings
Helmick et al.
Journal of Agricultural and Food Chemistry, 42, 2541-2544 (1994)
Palladium-Assisted Formation of Carbon- Carbon Bonds. 8.1 Synthesis and Reactivity toward Internal Alkynes, Carbon Monoxide, and Isocyanides of Orthopalladated Dibenzylamine Complexes
Vicente et al.
Organometallics, 18, 2683-2693 (1999)
Nitrosative cleavage of tertiary amines
Smith et al.
Journal of the American Chemical Society, 89, 1147-1157 (1967)
D W Thompson
Journal of pharmaceutical sciences, 71(5), 536-538 (1982-05-01)
A GLC method is described for the determination of iminodibenzyl and desipramine impurities in imipramine hydrochloride and its formulated products. These impurities were extracted from an alkaline solution with a mixture of 30% methylene chloride in hexane for chromatography on
Sean D Donevan et al.
Epilepsia, 44(10), 1274-1279 (2003-09-27)
Previously we demonstrated that L-(+)-beta-hydroxybutyrate (L-BHB), acetoacetate (ACA), acetone, and dibenzylamine (DBA) were anticonvulsant in an audiogenic seizure-susceptible model, and that DBA was a bioactive contaminant identified in commercial lots of L-BHB. In the present study, we asked whether these
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