质量水平
方案
97%
表单
powder
mp
143-146 °C (lit.)
SMILES字符串
Clc1cccc(Cl)c1C#N
InChI
1S/C7H3Cl2N/c8-6-2-1-3-7(9)5(6)4-10/h1-3H
InChI key
YOYAIZYFCNQIRF-UHFFFAOYSA-N
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应用
2,6-Dichlorobenzonitrile can be used as a starting material to synthesize:
- 2,6-Dichlorobenzaldehyde using lithium N, N′-dimethylethylenediaminoaluminum hydride as a reducing agent.
- 5-(2,6-Dichlorophenyl)-2H-tetrazole via gold-catalyzed nucleophilic (3 + 2) cycloaddition reaction with sodium azide.
- 2,6-Dichlorobenzamide via hydrolysis using potassium tert-butoxide as a catalyst.
- Chloro-aminoindazole by reacting with hydrazine monohydrate.
- 2,6-Dichlorobenzenecarboselenoamide by treating with Woollins′ reagent.
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Dermal - Aquatic Chronic 2
储存分类代码
11 - Combustible Solids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
农药列管产品
Selective conversion of aromatic nitriles to aldehydes by lithium N, N'-dimethylethylenediaminoaluminum hydride
Cha Jin-Soon, et al.
Bulletin of the Korean Chemical Society,, 23(12), 1697-1698 (2002)
The discovery and development of a safe, practical synthesis of ABT-869
Kruger AW, et al.
Organic Process Research & Development, 13(6), 1419-1425 (2009)
Transition-metal-free hydration of nitriles using potassium tert-butoxide under anhydrous conditions
Midya GC, et al.
The Journal of Organic Chemistry, 80(8), 4148-4151 (2015)
Synthetic application of gold nanoparticles and auric chloride for the synthesis of 5-substituted 1 H-tetrazoles
Kumar S, et al.
Royal Society of Chemistry Advances, 5(28), 21651-21658 (2015)
Synthesis of primary arylselenoamides by reaction of aryl nitriles with Woollins' reagent
Hua Guoxiong, et al.
Organic Letters, 8(23), 5251-5254 (2006)
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