F13207
4-氟苯酚
99%
别名:
4-氟苯酚, 对氟苯酚
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关于此项目
线性分子式:
FC6H4OH
化学文摘社编号:
分子量:
112.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-736-0
Beilstein/REAXYS Number:
1362752
MDL number:
Assay:
99%
InChI key
RHMPLDJJXGPMEX-UHFFFAOYSA-N
InChI
1S/C6H5FO/c7-5-1-3-6(8)4-2-5/h1-4,8H
SMILES string
Oc1ccc(F)cc1
assay
99%
bp
185 °C (lit.)
Quality Level
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signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
154.4 °F - closed cup
flash_point_c
68 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Alexandria Harkey et al.
Biotechnology letters, 34(9), 1725-1731 (2012-05-29)
Cytochrome P450(BM3)-F87G catalyzed the oxidative defluorination of 4-fluorophenol, followed by reduction of the resulting benzoquinone to hydroquinone via the NADPH P450-reductase activity of the enzyme. The k (cat) and K (m) for this reaction were 71 ± 5 min(-1) and
Manfred Lehnig et al.
Organic & biomolecular chemistry, 4(4), 721-729 (2006-02-10)
Peroxynitric acid (O2NOOH) nitrates L-tyrosine and related compounds at pH 2-5. During reaction with O2(15)NOOH in the probe of a 15N NMR spectrometer, the NMR signals of the nitration products of L-tyrosine, N-acetyl-L-tyrosine, 4-fluorophenol and 4-methoxyphenylacetic acid appear in emission
A M Osman et al.
Chemico-biological interactions, 104(2-3), 147-164 (1997-05-02)
The present study shows that MP8 in the presence of H2O2 is able to catalyze the rupture of the stable carbon-fluorine bond of 4-fluorophenol, used as a model substrate for the oxidative dehalogenation reaction. 1,4-Benzoquinone was shown to be the
Tobias L Ross et al.
Molecules (Basel, Switzerland), 16(9), 7621-7626 (2011-09-09)
4-[(18)F]Fluorophenol is a versatile synthon for the synthesis of more complex radiopharmaceuticals bearing a 4-[(18)F]fluorophenoxy moiety. In order to prepare 4-[(18)F]fluorophenol in no-carrier-added (n.c.a.) form only a nucleophilic labelling method starting from [(18)F]fluoride is suitable. In this paper a new
Thomas Ludwig et al.
Nuclear medicine and biology, 29(2), 255-262 (2002-02-02)
This paper describes the improved synthesis of n.c.a. 4- 18F]fluorophenol for the preparation of 18F-labeled alkylarylethers. Nucleophilic fluorination of substituted benzophenone derivatives yielded n.c.a. 4- 18F]fluoro-4'-substituted benzophenones with 80- 90% RCY, which were converted to benzoic acid phenylesters by treatment
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