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关于此项目
经验公式(希尔记法):
C3H6N2O
化学文摘社编号:
分子量:
86.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-436-4
Beilstein/REAXYS Number:
106252
MDL number:
产品名称
2-咪唑烷酮, 96%
InChI key
YAMHXTCMCPHKLN-UHFFFAOYSA-N
InChI
1S/C3H6N2O/c6-3-4-1-2-5-3/h1-2H2,(H2,4,5,6)
SMILES string
O=C1NCCN1
assay
96%
mp
129-132 °C (lit.)
Quality Level
Gene Information
human ... EPHX2(2053)
mouse ... Ephx2(13850)
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Application
用于合成以下物质的反应物:
反应物用于:
- 来源于非手性前体的手性微孔材料
- 通过微波辅助钯催化羰基化,合成芳基和杂芳基 N-酰基脲
- 一种高水溶性肽基人嗜中性粒细胞弹性蛋白酶抑制剂
- 通过氰基乙酰化合成杂环,用于抗菌应用
反应物用于:
- 使用杂芳族甲苯磺酸酯,Pd-催化的 C-N 键形成
- 活化烯烃的氧化酰胺化
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - STOT RE 2
target_organs
Thyroid
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Mette L H Mantel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(18), 5437-5442 (2010-04-09)
A protocol for the palladium(0)-catalyzed amidation of heteroaromatic tosylates was successfully developed. The methodology proved to be effective for a variety of heteroaryl tosylates including the pyridine, pyrimidine, quinoline and quinoxaline ring systems. Successful carbon-nitrogen bond formation with these heteroaryl
New Synthesis of Aryl and Heteroaryl N-Acylureas via Microwave-Assisted Palladium-Catalyzed Carbonylation
D. Liptrot, et al.,
Advanced Synthesis & Catalysis, 352, 2183-2188 (2010)
Oxidative amidation of activated alkenes using Pd(OAc)2 as a catalyst precursor
X. Liu and K. K. Hii,
European Journal of Organic Chemistry, 27, 5181-5189 (2010)
Synthesis and antimicrobial activity of new heterocycles obtained using cyanoacetylation
Sh. M. Abu-Bakr, et al.,
Pharmaceutical Chemistry Journal, 44, 433-437 (2010)
Yasunao Inoue et al.
Bioorganic & medicinal chemistry, 17(21), 7477-7486 (2009-10-09)
A series of peptide-based transition-state human neutrophil elastase (HNE) inhibitors with N-terminal acidic moieties were synthesized and their inhibitory activity against HNE was evaluated both in vitro and in vivo. Our results show that compounds containing cyclic amide bridged acidic
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