M35304
氯甲酸甲酯
99%
别名:
MCF, 氯甲酸甲酯
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线性分子式:
ClCOOCH3
化学文摘社编号:
分子量:
94.50
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-187-3
Beilstein/REAXYS Number:
605437
MDL number:
Assay:
99%
产品名称
氯甲酸甲酯, 99%
InChI
1S/C2H3ClO2/c1-5-2(3)4/h1H3
InChI key
XMJHPCRAQCTCFT-UHFFFAOYSA-N
SMILES string
COC(Cl)=O
vapor density
3.26 (vs air)
vapor pressure
4.8 psi ( 20 °C)
assay
99%
autoignition temp.
905 °F
refractive index
n20/D 1.387 (lit.)
bp
70-72 °C (lit.)
density
1.223 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
氯甲酸甲酯（MCF）常用于官能团的衍生化，如羧酸、胺和酚。
MCF还能用于：
MCF还能用于：
- 活化3-酰基吡啶，用于与炔基锡试剂进行亲核加成，形成2,3-二取代的1,2-二氢吡啶。
- 末端炔烃的氯酯化反应，形成β-氯-α,β-不饱和酯。
- 作为亲电试剂，介导吡啶与二烷基锂或二芳基铜酸锂的反应，生成4-取代的1,4-二氢吡啶衍生物。
- 将硝酸盐转化为甲氧基羰基硝酸盐。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
50.0 °F - closed cup
flash_point_c
10 °C - closed cup
法规信息
监管及禁止进口产品
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Kathleen F Smart et al.
Nature protocols, 5(10), 1709-1729 (2010-10-05)
This protocol describes an analytical platform for the analysis of intra- and extracellular metabolites of microbial cells (yeast, filamentous fungi and bacteria) using gas chromatography-mass spectrometry (GC-MS). The protocol is subdivided into sampling, sample preparation, chemical derivatization of metabolites, GC-MS
M G Zampolli et al.
Journal of chromatography. A, 1150(1-2), 162-172 (2007-01-16)
This work describes a GC-MS method for enantioselective separation of amino acids. The method is based on a derivatization reaction which employs a mixture of alkyl chloroformate-alcohol-pyridine, as reagents to obtain the N(O,S)-alkyl alkoxy carbonyl esters of amino acids. Various
Thibaut D J Delplancke et al.
Scientific reports, 8(1), 36-36 (2018-01-10)
The hair metabolome has been recognized as a valuable source of information in pregnancy research, as it provides stable metabolite information that could assist with studying biomarkers or metabolic mechanisms of pregnancy and its complications. We tested the hypothesis that
Reaction of Cuprate Reagents with Pyridine in the Presence of Chloroformate. A Novel Synthesis of 1, 4-Dihydropyridine Derivatives.
Piers E and Soucy M
Canadian Journal of Chemistry, 52(20), 3563-3564 (1974)
Ting-Li Han et al.
PloS one, 8(8), e71364-e71364 (2013-08-21)
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