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Merck
CN

P31205

苯丙炔酸

99%

别名:

苯基丙炔酸

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关于此项目

线性分子式:
C6H5C≡CCOOH
化学文摘社编号:
分子量:
146.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-285-8
Beilstein/REAXYS Number:
742587
MDL number:
Assay:
99%
Form:
crystals
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InChI key

XNERWVPQCYSMLC-UHFFFAOYSA-N

InChI

1S/C9H6O2/c10-9(11)7-6-8-4-2-1-3-5-8/h1-5H,(H,10,11)

SMILES string

OC(=O)C#Cc1ccccc1

assay

99%

form

crystals

Quality Level

storage temp.

2-8°C

Application

苯丙酸可以:
  • 在三氟化硼 · 二乙基醚的存在下与 2--丁氧基吡啶反应生成相应的 -丁酯。
  • 与芳基卤化物如 -氯碘苯和 1-氯-4-碘苯发生脱羧偶联。
  • 发生卤代脱羧反应生成 1-卤代炔。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Neil R McIntyre et al.
Journal of enzyme inhibition and medicinal chemistry, 31(4), 551-562 (2015-05-30)
Peptidylglycine α-amidating monooxygenase (PAM) is a bifunctional enzyme that catalyzes the final reaction in the maturation of α-amidated peptide hormones. Peptidylglycine α-hydroxylating monooxygenase (PHM) is the PAM domain responsible for the copper-, ascorbate- and O2-dependent hydroxylation of a glycine-extended peptide.
M Zieliński et al.
Isotopes in environmental and health studies, 37(3), 239-252 (2002-04-02)
13C kinetic isotope effect (KIE) in the decarboxylation of phenylpropiolic acid (PPA) in tetralin medium (Tn) has been determined at 409-432 K and found to be of magnitude similar to the 13C KIE observed in the decarboxylation of malonic acid
Rocío Gómez-Vásquez et al.
Annals of botany, 94(1), 87-97 (2004-05-18)
Control of diseases in the key tropical staple, cassava, is dependent on resistant genotypes, but the innate mechanisms are unknown. The aim was to study phenylpropanoids and associated enzymes as possible defence components. Phenylalanine ammonia-lyase (PAL), phenylpropanoids and peroxidases (POD)
Palladium-catalyzed decarboxylative cross-coupling of alkynyl carboxylic acids with arylboronic acids.
Feng C and Loh T P
Chemical Communications (Cambridge, England), 46(26), 4779-4781 (2010)
Elizabeth Joubert et al.
Food chemistry, 136(2), 1078-1085 (2012-11-06)
Z-2-(β-d-glucopyranosyloxy)-3-phenylpropenoic acid (PPAG), a compound postulated to contribute to the taste and mouthfeel of fermented rooibos tea (Aspalathus linearis), was isolated from unfermented rooibos plant material. Its structure was unequivocally confirmed by LC-MS, -MS(2), FT-IR and NMR of the underivatised

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