P73404
吡咯-2-甲醛
98%
别名:
2-甲酰基吡咯
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关于此项目
经验公式（希尔记法）:
C5H5NO
化学文摘社编号:
分子量:
95.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-705-5
Beilstein/REAXYS Number:
105745
MDL number:
Assay:
98%
Form:
crystals
产品名称
吡咯-2-甲醛, 98%
InChI
1S/C5H5NO/c7-4-5-2-1-3-6-5/h1-4,6H
InChI key
ZSKGQVFRTSEPJT-UHFFFAOYSA-N
SMILES string
[H]C(=O)c1ccc[nH]1
assay
98%
form
crystals
bp
217-219 °C (lit.)
mp
43-46 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
- 用于检测铜绿假单胞菌的基于嘧啶的荧光有机纳米粒子探针：这项研究使用吡咯-2-甲醛开发了一种基于嘧啶的荧光纳米粒子探针，用于检测铜绿假单胞菌，增强了微生物学的诊断能力（Kaur G等人，2015年）。
General description
2-吡咯甲醛是一种杂环合成砌块，由2位连接甲酰基的吡咯环组成，用于生产各种生物活性物质。 高度官能化的2-吡咯甲醛已用作中间体制备吡咯低聚物大环。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
224.6 °F - closed cup
flash_point_c
107 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Corey A Rice et al.
The Journal of chemical physics, 126(13), 134313-134313 (2007-04-14)
Intermolecular interactions relevant for antiparallel beta-sheet formation between peptide strands are studied by Fourier transform infrared spectroscopy of the low temperature, vacuum-isolated model compound pyrrole-2-carboxaldehyde and its dimer in the N-H and C=O stretching range. Comparison to quantum chemical predictions
Yasushi Hikida et al.
Nature protocols, 5(7), 1312-1323 (2010-07-03)
Methods for fluorescent probing at a defined position of RNA provide powerful tools for analyzing the local structural conformation of functional RNA molecules by tracking fluorescence changes. In this article, we describe the site-specific fluorescent probing of RNA by transcription
Ryuya Fukunaga et al.
Biochemical and biophysical research communications, 372(3), 480-485 (2008-05-28)
An unnatural base pair between 7-(2-thienyl)-imidazo[4,5-b]pyridine (Ds) and pyrrole-2-carbaldehyde (Pa) could expand the genetic alphabet and allow the incorporation of non-standard amino acids into proteins at defined positions. For this purpose, we synthesized tRNAs bearing Pa at the anticodon and
Aaron R Coffin et al.
The Journal of organic chemistry, 71(17), 6678-6681 (2006-08-12)
A regiocontrolled synthesis of 3,4-disubstituted pyrrole-2-carboxaldehydes was completed in two steps from acyclic starting materials. A Barton-Zard pyrrole synthesis between N-methoxy-N-methyl-2-isocyanoacetamide and alpha-nitroalkenes or beta-nitroacetates provided N-methoxy-N-methyl pyrrole-2-carboxamides (pyrrole Weinreb amides), which were converted into the corresponding pyrrole-2-carboxaldehydes by treatment
Tsuneo Mitsui et al.
Journal of the American Chemical Society, 125(18), 5298-5307 (2003-05-02)
An unnatural hydrophobic base, pyrrole-2-carbaldehyde (denoted as Pa), was developed as a specific pairing partner of 9-methylimidazo[(4,5)-b]pyridine (Q). The Q base is known to pair with 2,4-difluorotoluene (F) as an isostere of the A-T pair, and F also pairs with
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