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Merck
CN

P73404

吡咯-2-甲醛

98%

别名:

2-甲酰基吡咯

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关于此项目

经验公式(希尔记法):
C5H5NO
化学文摘社编号:
分子量:
95.10
Beilstein:
105745
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平

方案

98%

表单

crystals

沸点

217-219 °C (lit.)

mp

43-46 °C (lit.)

储存温度

2-8°C

SMILES字符串

[H]C(=O)c1ccc[nH]1

InChI

1S/C5H5NO/c7-4-5-2-1-3-6-5/h1-4,6H

InChI key

ZSKGQVFRTSEPJT-UHFFFAOYSA-N

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一般描述

2-吡咯甲醛是一种杂环合成砌块,由2位连接甲酰基的吡咯环组成,用于生产各种生物活性物质。 高度官能化的2-吡咯甲醛已用作中间体制备吡咯低聚物大环。

应用


  • 用于检测铜绿假单胞菌的基于嘧啶的荧光有机纳米粒子探针:这项研究使用吡咯-2-甲醛开发了一种基于嘧啶的荧光纳米粒子探针,用于检测铜绿假单胞菌,增强了微生物学的诊断能力(Kaur G等人,2015年)。


储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

224.6 °F - closed cup

闪点(°C)

107 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Barbara Michela Giuliano et al.
The journal of physical chemistry. A, 114(7), 2506-2517 (2010-01-30)
Monomeric pyrrole-2-carbaldehyde (P2C) was isolated in low-temperature argon and xenon matrices, and its UV-induced photochemistry was studied. The structures of the reagent as well as the reaction photoproducts were characterized by FTIR spectroscopy. Interpretation of the experimental results was assisted
Regiocontrolled synthesis of pyrrole-2-carboxaldehydes and 3-pyrrolin-2-ones from pyrrole Weinreb amides
Coffin, Aaron R and Roussell, et al.
The Journal of Organic Chemistry, 71, 6678-6681 (2006)
Tsuneo Mitsui et al.
Journal of the American Chemical Society, 125(18), 5298-5307 (2003-05-02)
An unnatural hydrophobic base, pyrrole-2-carbaldehyde (denoted as Pa), was developed as a specific pairing partner of 9-methylimidazo[(4,5)-b]pyridine (Q). The Q base is known to pair with 2,4-difluorotoluene (F) as an isostere of the A-T pair, and F also pairs with
Takumi Ishizuka et al.
Chemical communications (Cambridge, England), 48(88), 10835-10837 (2012-10-04)
Toward new biotechnology by genetic alphabet expansion, we developed an efficient site-specific labeling method for large RNA molecules. The combination of unnatural base pair transcription and post-transcriptional modification by click chemistry enables simple RNA labeling with a wide variety of
Corey A Rice et al.
The Journal of chemical physics, 126(13), 134313-134313 (2007-04-14)
Intermolecular interactions relevant for antiparallel beta-sheet formation between peptide strands are studied by Fourier transform infrared spectroscopy of the low temperature, vacuum-isolated model compound pyrrole-2-carboxaldehyde and its dimer in the N-H and C=O stretching range. Comparison to quantum chemical predictions

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