T67806
亚磷酸三异丙酯
95%
别名:
三-2-丙基亚磷酸酯, 三异丙基亚磷酸酯, 三异丙氧基膦, 亚磷酸异丙酯
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关于此项目
线性分子式:
[(CH3)2CHO]3P
化学文摘社编号:
分子量:
208.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-130-0
Beilstein/REAXYS Number:
1701528
MDL number:
Assay:
95%
InChI key
SJHCUXCOGGKFAI-UHFFFAOYSA-N
InChI
1S/C9H21O3P/c1-7(2)10-13(11-8(3)4)12-9(5)6/h7-9H,1-6H3
SMILES string
CC(C)OP(OC(C)C)OC(C)C
vapor pressure
<2 mmHg ( 20 °C)
assay
95%
Quality Level
bp
63-64 °C/11 mmHg (lit.)
density
0.844 g/mL at 25 °C (lit.)
Application
亚磷酸三异丙酯可作为反应剂：
它还可在光延反应中替代三苯基膦，方便产物分离。
- 与钌亚茚基 (ruthenium indenylidene) 复合物形成复分解反应的第一代复合物。
- 在Perkow反应中用于合成含极化碳碳双键的化合物。
- 与芳香胺和亚硝酸异戊酯反应合成膦酰肼。
它还可在光延反应中替代三苯基膦，方便产物分离。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Skin Irrit. 2
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
154.4 °F - closed cup
flash_point_c
68 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Ruthenium indenylidene ?1st generation? olefin metathesis catalysts containing triisopropyl phosphite
Guidone S, et al.
Beilstein Journal of Organic Chemistry, 11, 1520-1520 (2015)
Mitsunobu reactions of nucleoside analogs using triisopropyl phosphite-DIAD
Veliz EA and Beal PA
Tetrahedron Letters, 47(18), 3153-3156 (2006)
Nef-isocyanide-Perkow synthesis of new polarized olefins containing 2-dicyanomethylene-2, 3-dihydrothiazole and 2-dicyanomethylene-1, 3-dithiole moieties
Yavari I, et al.
Tetrahedron, 69(11), 2462-2467 (2013)
Su Mei Liu et al.
Marine pollution bulletin, 60(9), 1591-1599 (2010-04-30)
Inorganic or bulk organic chemical indicators, including organic carbon (OC), total nitrogen, organic nitrogen (ON), fixed ammonium (N(fix)), exchangeable ammonium, exchangeable nitrate, organic phosphorus (OP), inorganic phosphorus (IP), and biogenic silica (BSi), were examined in a 3-m core collected in
Convenient synthesis of phosphonohydrazines from arylamines
Kent GT, et al.
Tetrahedron Letters, 57(19), 2097-2099 (2016)
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