Quality Level
assay
96%
refractive index
n20/D 1.378 (lit.)
bp
74 °C/730 mmHg (lit.)
mp
6 °C (lit.)
density
0.793 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
[H]C(=O)C(C)(C)C
InChI
1S/C5H10O/c1-5(2,3)4-6/h4H,1-3H3
InChI key
FJJYHTVHBVXEEQ-UHFFFAOYSA-N
Application
用于研究醛与 TMS-CN 和手性钒(V)-salen 络合物的不对称氰化。
羟醛缩合反应中常用的结构单元。
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
3.2 °F - closed cup
flash_point_c
-16 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Adrian Méndez et al.
Molecules (Basel, Switzerland), 25(21) (2020-11-04)
Singlet oxygen ene reactions produce 2-(tert-butyl)-4a-hydroperoxy-3-methyl-2,4a, 5,6,7,8-hexahydroquinazolin-4(3H)-one quantitatively during diffusion crystallization of 2-(tert-butyl)-3-methyl-2,3,5,6,7,8-hexahydroquinazolin-4(1H)-one in n-hexane/CH2Cl2 solvent mixture. To confirm this photo-oxidation, a 1H-NMR study in CDCl3 was performed with exposure to ambient conditions (light and oxygen), with neither additional reactants
Li Huang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(17), 5302-5313 (2012-03-22)
The catalytic asymmetric aziridination of imines and diazo compounds (AZ reaction) mediated by boroxinate catalysts derived from the VANOL and VAPOL ligands was investigated with chiral imines derived from five different chiral, disubstituted, methyl amines. The strongest matched and mismatched
Tetrahedron Asymmetry, 17, 2659-2659 (2006)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| T71501-100ML | 04061836696856 |
| T71501-5ML | 04061837372322 |
| T71501-25ML | 04061837372315 |

