T89206
托品酸
98%
别名:
α-羟甲基苯乙酸, 3-羟基-2-苯基丙酸
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关于此项目
线性分子式:
C6H5CH(CH2OH)CO2H
化学文摘社编号:
分子量:
166.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-020-6
Beilstein/REAXYS Number:
2209199
MDL number:
Assay:
98%
InChI
1S/C9H10O3/c10-6-8(9(11)12)7-4-2-1-3-5-7/h1-5,8,10H,6H2,(H,11,12)
InChI key
JACRWUWPXAESPB-UHFFFAOYSA-N
SMILES string
OCC(C(O)=O)c1ccccc1
assay
98%
Quality Level
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Application
托品酸可作为下列反应的底物：
- Dowex H+/NaI催化系统下的羧酸和醇的酯化反应。
- 环戊酯肽的多步合成反应。
- 与四氰苯(TCNB)通过多组分光化学反应合成异香豆素衍生物。
托品酸用于合成 (-)-樟柳碱 、阿托品和莨菪碱。
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Synthesis of conformationally restricted cyclic pentadepsipeptides via direct amide cyclization
Koch KN, et al.
Tetrahedron, 57(12), 2311-2326 (2001)
Green and Efficient Esterification Method Using Dried Dowex H+/NaI Approach
Turhanen PA, et al.
ACS Omega, 4(5), 8974-8984 (2019)
Photo-multicomponent reactions leading to the construction of isocoumarins and large ring lactone precursors
Lu Z, et al.
Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society for Photobiology, 8(2), 217-223 (2009)
Junbiao Chang et al.
European journal of medicinal chemistry, 41(3), 397-400 (2006-01-18)
-Anisodine (l-6,7-epoxy-3-tropyl-alpha-hydroxytropate), which was isolated from the medicinal plant Scopolia tanguticus Maxim, was the first efficiently prepared using 6-beta-acetyltropine as the starting material via a key step of the Sharpless asymmetric dihydroxylation (AD). The intermediate compounds 10 and 11 showed
Tropane alkaloids in pharmaceutical and phytochemical analysis.
Gadzikowska, MARIA and Grynkiewicz, GRZEGORZ
Acta Poloniae Pharmaceutica, 59(2), 149-160 (2002)
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