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Merck
CN

W213403

二苯甲酮

FCC, FG

别名:

NSC 8077, 二苯基甲酮, 二苯基酮

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线性分子式:
(C6H5)2CO
化学文摘社编号:
119-61-9
分子量:
182.22
FEMA Number:
2134
Council of Europe no.:
166
UNSPSC Code:
12164502
PubChem Substance ID:
24900871
Flavis number:
7.032
EC Number:
204-337-6
NACRES:
NA.21
MDL number:
MFCD00003076
Beilstein/REAXYS Number:
1238185

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SMILES string

O=C(C1=CC=CC=C1)C2=CC=CC=C2

InChI

1S/C13H10O/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H

InChI key

RWCCWEUUXYIKHB-UHFFFAOYSA-N

biological source

synthetic

grade

FG, Kosher

agency

meets purity specifications of JECFA

reg. compliance

EU Regulation 1334/2008 & 178/2002, FCC

vapor pressure

1 mmHg ( 108 °C)

assay

99%

form

crystals or chunks (Crystalline)

bp

305 °C (lit.)

mp

47-51 °C (lit.)

solubility

ethanol: soluble 100 mg/mL, clear, colorless (80% ethanol)

application(s)

flavors and fragrances

documentation

see Safety & Documentation for available documents

food allergen

no known allergens

organoleptic

geranium; fruity; sweet

Quality Level

400

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General description

Benzophenone is an aromatic carbonyl compound. Photoinitiated free radical polymerization of benzophenone in the presence of N-methyldiethanolamine as a coinitiator has been reported. Polymeric benzophenone photoinitiator (PBP) has been synthesized by using “Thiol-ene Click Chemistry” and characterized by 1H NMR, FTIR, UV, and phosphorescence spectroscopies.

Application

Benzophenone is suitable anchoring agent used for the surface modification of graphene. It may be used in the preparation of N-(diphenylmethylene)-N′-(tert-butoxycarbonyl)-N′- (4-bromophenyl)-p-phenylenediamine.

pictograms

Health hazard
GHS08

signalword

Danger

Hazard Classifications

Aquatic Chronic 3 - Carc. 1B - STOT RE 2 Oral

target_organs

Liver,Kidney

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 1

flash_point_f

280.4 °F - closed cup

flash_point_c

138 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBQ1810
SHBL3213
MKCD7836
MKBW7498V
MKBV9303V

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Synthesis of main chain polymeric benzophenone photoinitiator via thiol-ene click chemistry and Its use in free radical polymerization.
Temel G, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 48(23), 5306-5312 (2010)
Photopolymerization and photophysical properties of amine linked benzophenone photoinitiator for free radical polymerization.
Temel G, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 219(1), 26-31 (2011)
Preparation and properties of poly (methacrylamide) s containing oligoaniline side chains.
Chen R and Benicewicz BC.
Macromolecules, 36(17), 6333-6339 (2003)
A powerful tool for graphene functionalization: Benzophenone mediated UV-grafting.
Roppolo I, et al.
Carbon, 77, 226-235 (2014)
Claire Chatalova-Sazepin et al.
Angewandte Chemie (International ed. in English), 54(18), 5443-5446 (2015-03-05)
A three-component carboetherification of unactivated alkenes has been developed allowing the rapid building of complexity from simple starting materials. A wide range of α-substituted styrenes underwent smooth reactions with unactivated alkyl nitriles and alcohols to afford γ-alkoxy alkyl nitriles with
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