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经验公式(希尔记法):
C8H12N2O3S
化学文摘社编号:
分子量:
216.26
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
208-993-4
Beilstein/REAXYS Number:
15080
MDL number:
Assay:
96%
Form:
powder
InChI key
NGHVIOIJCVXTGV-ALEPSDHESA-N
InChI
1S/C8H12N2O3S/c1-8(2)4(7(12)13)10-5(11)3(9)6(10)14-8/h3-4,6H,9H2,1-2H3,(H,12,13)/t3-,4+,6-/m1/s1
SMILES string
CC1(C)S[C@@H]2[C@H](N)C(=O)N2[C@H]1C(O)=O
assay
96%
form
powder
optical activity
[α]22/D +276.3°, c = 1.2 in 0.1 M HCl
mp
198-200 °C (dec.) (lit.)
antibiotic activity spectrum
Gram-positive bacteria
mode of action
cell wall synthesis | interferes
storage temp.
2-8°C
Quality Level
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General description
(+)-6-氨基青霉烷酸是不同青霉素的核心部分。可由苄青霉素硅烷基酯通过酰胺键断裂制备。(+)-6-氨基青霉烷酸包被在银纳米颗粒 (6APA-AgNPs) 上,使其具有检测人红细胞中铬 (IV) 的能力。
化学结构式:β-内酰胺
Application
它与较高氨基酸席夫碱反应形成相应的β-内酰胺衍生物4
(+)-6-氨基青霉烷酸可作为原料,用于通过界面缩聚反应与有机锡二卤化物反应合成(6S,7S)-头孢菌素和有机锡多胺酯。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
6-aminopenicillanic acid.
Rolinson GN.
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An efficient nonenzymatic conversion of benzylpenicillin to 6-aminopenicillanic acid.
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Chromium scavenging ability of silver nanoparticles in human erythrocytes, real samples and their effect on the catalase enzyme.
Rasheed W, et al.
New. J. Chem., 40(4), 3793-3802 (2016)
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Optimality and robustness in quorum sensing (QS)-mediated regulation of a costly public good enzyme.
Anand Pai et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(48), 19810-19815 (2012-11-13)
Bacteria secrete a variety of public good exoproducts into their environment. These exoproducts are typically produced under the control of quorum sensing (QS), a signaling mechanism by which bacteria sense and respond to changes in their density. QS seems to
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