C102504
氧化环己烯
98%
别名:
1,2-环氧环己烷, 7-氧杂二环[4.1.0]庚烷
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关于此项目
经验公式（希尔记法）:
C6H10O
化学文摘社编号:
分子量:
98.14
Beilstein:
383568
EC 号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23
方案
98%
表单
liquid
自燃温度
703 °F
expl. lim.
12.36 %
折射率
n20/D 1.452 (lit.)
沸点
129-130 °C (lit.)
密度
0.97 g/mL at 25 °C (lit.)
SMILES字符串
C1CCC2OC2C1
InChI
1S/C6H10O/c1-2-4-6-5(3-1)7-6/h5-6H,1-4H2
InChI key
ZWAJLVLEBYIOTI-UHFFFAOYSA-N
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应用
- Polymeric carbon nitride with internal np homojunctions for efficient photocatalytic CO2 reduction coupled with cyclohexene oxidation：以氮化碳聚合物为催化剂，采用氧化环己烯进行CO2的光催化还原反应。CO2还原反应可解决环境问题，伴随的偶联反应可高效转化氧化环己烯(W Zhen et al., 2021)。
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 1
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Liping Guo et al.
Dalton transactions (Cambridge, England : 2003), (27)(27), 5406-5410 (2009-07-01)
A new, natural lysine-based (salen)Cr(III)Cl ((lys-salen)Cr(III)Cl) complex was prepared and its catalytic activity for the copolymerization of CO(2) and cyclohexene oxide (CHO) was described in the presence of PPNCl (PPN(+) = bis(triphenylphosphoranylidene)ammonium) as cocatalyst. The influence of the reaction time
Highly active dizinc catalyst for the copolymerization of carbon dioxide and cyclohexene oxide at one atmosphere pressure.
Michael R Kember et al.
Angewandte Chemie (International ed. in English), 48(5), 931-933 (2008-12-31)
Matteo Proverbio et al.
Polymers, 11(7) (2019-07-25)
Cyclohexene oxide (CHO) and phthalic anhydride (PA) have been reacted in the presence of commercial salen-type complexes with different metals Cr (1), Al (2), and Mn (3) in combination with 4-(dimethylamino) pyridine (DMAP), bis-(triphenylphosphorydine) ammonium chloride (PPNCl) and bis-(triphenylphosphoranylidene)ammonium azide
Brahmam Pujala et al.
The Journal of organic chemistry, 76(21), 8768-8780 (2011-09-09)
The scope and limitations of metal tetrafluoroborates have been studied for epoxide ring-opening reaction with amines, and Zn(BF(4))(2)·xH(2)O has been found to be a mild and efficient catalyst affording high yields under solvent-free conditions at rt with excellent chemo-, regio-
Fabian Jutz et al.
Journal of the American Chemical Society, 133(43), 17395-17405 (2011-10-07)
The reaction kinetics of the copolymerization of carbon dioxide and cyclohexene oxide to produce poly(cyclohexene carbonate), catalyzed by a dizinc acetate complex, is studied by in situ attenuated total reflectance infrared (ATR-IR) and proton nuclear magnetic resonance ((1)H NMR) spectroscopy.
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