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经验公式(希尔记法):
C5H6O
化学文摘社编号:
分子量:
82.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-213-0
Beilstein/REAXYS Number:
1446054
MDL number:
产品名称
2-环戊烯-1-酮, 98%
InChI key
BZKFMUIJRXWWQK-UHFFFAOYSA-N
InChI
1S/C5H6O/c6-5-3-1-2-4-5/h1,3H,2,4H2
SMILES string
O=C1CCC=C1
assay
98%
form
liquid
refractive index
n20/D 1.481 (lit.)
bp
64-65 °C/19 mmHg (lit.)
density
0.98 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
用于许多加成反应的多功能亲电试剂,包括有机铜亲核试剂的共轭加成、与硅烯醇醚和硅氧烷的 Michael 加成、Diels-Alder 环加成以及磷鎓基硅烷化。
Jesse R Poganik et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 33(12), 14636-14652 (2019-11-02)
The nuclear factor erythroid 2-related factor 2 (Nrf2) signaling axis is a target of covalent drugs and bioactive native electrophiles. However, much of our understanding of Nrf2 regulation has been focused at the protein level. Here we report a post-transcriptional
Yoshihiro Sumiyoshi et al.
The Journal of chemical physics, 125(12), 124307-124307 (2006-10-04)
Pure rotational transitions in the ground state for Ar-OH and Ar-OD [Y. Ohshima et al., J. Chem. Phys. 95, 7001 (1991) and Y. Endo et al., Faraday Discuss. 97, 341 (1994)], those in the excited states of the OH vibration
Filippo De Simone et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(51), 14527-14538 (2011-11-25)
The Nazarov cyclization of divinyl ketones gives access to cyclopentenones. Replacing one of the vinyl groups by a cyclopropane leads to a formal homo-Nazarov process for the synthesis of cyclohexenones. In contrast to the Nazarov reaction, the cyclization of vinyl-cyclopropyl
Marc Revés et al.
Organic letters, 14(13), 3534-3537 (2012-06-28)
1,2,3,4-Tetramethyl-bicyclo[2.2.1]hepta-2,5-diene (TMNBD, for tetramethylnorbornadiene) has been prepared and used successfully as an acetylene equivalent in the synthesis of substituted cyclopentenones. TMNBD is easily accessible on a multigram scale and displays excellent reactivity toward the intermolecular Pauson-Khand reaction. Conjugate additions on
Tetrahedron Letters, 34, 6777-6777 (1993)
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