C116602
环丙甲酸
95%
别名:
环丙酸
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关于此项目
线性分子式:
C3H5CO2H
化学文摘社编号:
分子量:
86.09
MDL number:
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-162-5
Beilstein/REAXYS Number:
969839
Assay:
95%
Form:
liquid
InChI key
YMGUBTXCNDTFJI-UHFFFAOYSA-N
InChI
1S/C4H6O2/c5-4(6)3-1-2-3/h3H,1-2H2,(H,5,6)
SMILES string
OC(=O)C1CC1
assay
95%
form
liquid
Quality Level
refractive index
n20/D 1.438 (lit.)
bp
182-184 °C (lit.)
mp
14-17 °C (lit.)
density
1.081 g/mL at 25 °C (lit.)
storage temp.
2-8°C
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
161.6 °F - closed cup
flash_point_c
72 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Mei-Xiang Wang et al.
The Journal of organic chemistry, 68(2), 621-624 (2003-01-18)
Biotransformations of differently configured 2,2-dimethyl-3-substitued-cyclopropanecarbonitriles were studied using a nitrile hydratase/amidase-containing Rhodococcus sp. AJ270 whole-cell catalyst under very mild conditions. Although all of the cis-3-aryl-2,2-dimethylcyclopropanecarbonitriles appeared inert toward the biocatalyst, a number of racemic trans-isomers efficiently underwent a highly enantioselective
Hiroaki Yasukochi et al.
Organic & biomolecular chemistry, 6(3), 540-547 (2008-01-26)
We performed an efficient practical and systematic optical resolution method for gem-dihalo- and monohalocyclopropanecarboxylic acids and utilizing chiral 1,1'-binaphthol monomethyl ether (R)- as the key auxiliary. Direct esterification of with (R)- gave two 1R- and 1S-diastereomeric esters with marked different
M V Clos et al.
British journal of pharmacology, 118(4), 901-904 (1996-06-01)
1. The effect of 1-aminocyclopropanecarboxylic acid (ACPC), a partial agonist at the glycine site of the N-methyl-D-aspartate (NMDA) receptor complex that exhibits neuroprotective, anxiolytic and antidepressant-like actions, was investigated in a functional assay for presynaptic NMDA receptors. 2. NMDA (100
Perali Ramu Sridhar et al.
Chemical communications (Cambridge, England), 48(5), 756-758 (2011-12-03)
A stereoselective methodology was developed for the construction of C-spiro-glycosides in two steps involving bromonium ion activated solvolytic ring opening of sugar derived 1,2-cyclopropanecarboxylates followed by a one-pot dehydrohalogenation, intramolecular hetero-Michael addition (IHMA) and ester hydrolysis. The obtained spirocyclic lactols
Tetsuo Toraya et al.
Applied and environmental microbiology, 70(1), 224-228 (2004-01-09)
A new strain isolated from soil utilizes cyclopropanecarboxylate as the sole source of carbon and energy and was identified as Rhodococcus rhodochrous (H. Nishihara, Y. Ochi, H. Nakano, M. Ando, and T. Toraya, J. Ferment. Bioeng. 80:400-402, 1995). A novel
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