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C19686

2-Chloroacetophenone

Name: 2-Chloroacetophenone
Brand: ALDRICH

98%

别名:

ω-Chloroacetophenone, Phenacyl chloride

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关于此项目

线性分子式:

C₆H₅COCH₂Cl

化学文摘社编号:

532-27-4

分子量:

154.59

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24892454

EC Number:

208-531-1

Beilstein/REAXYS Number:

507950

MDL number:

MFCD00000933

Assay:

98%

Form:

crystals

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Quality Level

200

assay

98%

form

crystals

bp

244-245 °C (lit.)

mp

54-56 °C (lit.)

density

1.324 g/mL at 25 °C (lit.)

SMILES string

ClCC(=O)c1ccccc1

InChI

1S/C8H7ClO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

InChI key

IMACFCSSMIZSPP-UHFFFAOYSA-N

Gene Information

human ... PTPN6(5777)

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pictograms

GHS06,GHS08,GHS05

signalword

Danger

hcodes

H300,H311 + H331,H315,H318,H334,H335

pcodes

P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Efficient whole-cell biotransformation in a biphasic ionic liquid/water system.

Holger Pfruender et al.

Angewandte Chemie (International ed. in English), 43(34), 4529-4531 (2004-09-02)

Tear gasses CN, CR, and CS are potent activators of the human TRPA1 receptor.

Bert Brône et al.

Toxicology and applied pharmacology, 231(2), 150-156 (2008-05-27)

The TRPA1 channel is activated by a number of pungent chemicals, such as allylisothiocyanate, present in mustard oil and thiosulfinates present in garlic. Most of the known activating compounds contain reactive, electrophilic chemical groups, reacting with cysteine residues in the

Bioreduction of alpha-chloroacetophenone by whole cells of marine fungi.

Lenilson C Rocha et al.

Biotechnology letters, 31(10), 1559-1563 (2009-06-06)

The asymmetric reduction of 2-chloro-1-phenylethanone (1) by seven strains of marine fungi was evaluated and afforded (S)-(-)-2-chloro-1-phenylethanol with, in the best case, an enantiomeric excess of 50% and an isolated yield of 60%. The ability of marine fungi to catalyse

Thermal decomposition studies of riot control agent ω-chloroacetophenone (CN) by pyrolysis-gas chromatography-mass spectrometry.

Anil K Nigam et al.

Journal of hazardous materials, 184(1-3), 506-514 (2010-09-17)

Pyrolysis-GC/MS system with on-line micro-furnace was used to make rapid evaluation of ω-chloroacetophenone (CN) decomposition under inert thermal atmospheres. The volatile products evolved during pyrolysis were analyzed by thermal gravimetric analysis (TGA) and Py-GC/MS to obtain specific thermogram and pyrogram.

Asymmetric reduction of o-chloroacetophenone with Candida pseudotropicalis 104.

Qing Xie et al.

Biotechnology progress, 22(5), 1301-1304 (2006-10-07)

The asymmetric reduction of o-chloroacetophenone 1 with Candida pseudotropicalis 104 produced the corresponding (S)-1-(2-chloro-phenyl)-ethanol 2 with the enantiomeric excess (ee >99%) without addition of any cosolvent. The cell could tolerate high ketone 1 concentration of 233.8 mmol/L (i.e., 36 g/L)

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全球贸易项目编号

货号	GTIN
C19686-100G	04061833474884
C19686-500G	04061831835250

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