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关于此项目
线性分子式:
CH2=CClCN
化学文摘社编号:
分子量:
87.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
773744
Assay:
98%
Form:
liquid
InChI
1S/C3H2ClN/c1-3(4)2-5/h1H2
SMILES string
ClC(=C)C#N
InChI key
OYUNTGBISCIYPW-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.429 (lit.)
bp
88-89 °C (lit.)
mp
−65 °C (lit.)
density
1.096 g/mL at 25 °C (lit.)
Quality Level
Application
环加成反应中的通用试剂。
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Resp. Sens. 1 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
42.8 °F - closed cup
flash_point_c
6 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Journal of the Chemical Society. Chemical Communications, 814-814 (1993)
Asymmetric conjugate addition of oxindoles to 2-chloroacrylonitrile: a highly effective organocatalytic strategy for simultaneous construction of 1,3-nonadjacent stereocenters leading to chiral pyrroloindolines.
Xin Li et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(48), 14290-14294 (2010-12-01)
The Journal of Organic Chemistry, 58, 5200-5200 (1993)
Yi Wang et al.
Journal of the American Chemical Society, 128(12), 3928-3930 (2006-03-23)
Catalytic tandem asymmetric reactions constitute a powerful strategy for the asymmetric construction of nonadjacent stereocenters in acyclic molecules directly from achiral precursors. In this Communication, we report a highly enantioselective and diastereoselective addition of trisubstituted carbon donors to 2-chloroacrylonitrile catalyzed
A G Craan et al.
Toxicology, 56(1), 47-61 (1989-05-31)
The nephrotoxicity of glutathione (GSH) pathway metabolites derived from toluene (TOL), styrene (STYR), bromobenzene (BB), acrylonitrile (ACLN) and 2-chloroacrylonitrile (CACLN) were compared with that of dichlorovinylcysteine (DCVC), using renal brush border and basal-lateral uptake parameters as indices. Cysteine conjugates and
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