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Merck
CN

C22369

2-氯丙烯腈

98%

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关于此项目

线性分子式:
CH2=CClCN
化学文摘社编号:
分子量:
87.51
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
773744
Assay:
98%
Form:
liquid
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InChI

1S/C3H2ClN/c1-3(4)2-5/h1H2

SMILES string

ClC(=C)C#N

InChI key

OYUNTGBISCIYPW-UHFFFAOYSA-N

assay

98%

form

liquid

refractive index

n20/D 1.429 (lit.)

bp

88-89 °C (lit.)

mp

−65 °C (lit.)

density

1.096 g/mL at 25 °C (lit.)

Quality Level

Application

环加成反应中的通用试剂。

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 3 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Resp. Sens. 1 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

42.8 °F - closed cup

flash_point_c

6 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Journal of the Chemical Society. Chemical Communications, 814-814 (1993)
Asymmetric conjugate addition of oxindoles to 2-chloroacrylonitrile: a highly effective organocatalytic strategy for simultaneous construction of 1,3-nonadjacent stereocenters leading to chiral pyrroloindolines.
Xin Li et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(48), 14290-14294 (2010-12-01)
The Journal of Organic Chemistry, 58, 5200-5200 (1993)
Yi Wang et al.
Journal of the American Chemical Society, 128(12), 3928-3930 (2006-03-23)
Catalytic tandem asymmetric reactions constitute a powerful strategy for the asymmetric construction of nonadjacent stereocenters in acyclic molecules directly from achiral precursors. In this Communication, we report a highly enantioselective and diastereoselective addition of trisubstituted carbon donors to 2-chloroacrylonitrile catalyzed
A G Craan et al.
Toxicology, 56(1), 47-61 (1989-05-31)
The nephrotoxicity of glutathione (GSH) pathway metabolites derived from toluene (TOL), styrene (STYR), bromobenzene (BB), acrylonitrile (ACLN) and 2-chloroacrylonitrile (CACLN) were compared with that of dichlorovinylcysteine (DCVC), using renal brush border and basal-lateral uptake parameters as indices. Cysteine conjugates and

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