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D161608

N,N-二甲基肼

Name: N,N-二甲基肼
Brand: ALDRICH

98%

别名:

1,1-二甲基肼, 不对称二甲肼

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关于此项目

线性分子式:

(CH₃)₂NNH₂

化学文摘社编号:

57-14-7

分子量:

60.10

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24893497

EC Number:

200-316-0

Beilstein/REAXYS Number:

605261

MDL number:

MFCD00007628

Assay:

98%

Form:

liquid

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属性

vapor density

1.94 (vs air)

vapor pressure

103 mmHg ( 20 °C)

assay

98%

form

liquid

autoignition temp.

478 °F

expl. lim.

95 %

refractive index

n20/D 1.4075 (lit.)

bp

60-62 °C (lit.)

density

0.79 g/mL at 20 °C (lit.)

storage temp.

2-8°C

SMILES string

CN(C)N

InChI

1S/C2H8N2/c1-4(2)3/h3H2,1-2H3

InChI key

RHUYHJGZWVXEHW-UHFFFAOYSA-N

说明

Application

N，N-二甲基肼可与以下物质反应：

β-萘酚，经自由基胺化形成1-氨基-2-萘酚。
2-氯-和2，2-二氯-（溴）乙烯基酮，通过区域选择性杂环化形成3-取代的1-甲基（5-卤代）吡唑。
端炔，在TpRuCl（PPh₃）₂ （Tp =三（吡唑基）硼酸酯）的存在下形成腈。

N，N-二甲基肼与六水合氯化铁形成一种有效的还原系统，用于：

通过相应硝基醛的还原环化合成DNA结合吡咯并[2,1-c][1,4]苯并二氮杂（PBD）亚胺。
将各种硝基芳烃和叠氮基化合物分别转化为相应的苯胺和氨基化合物。

Biochem/physiol Actions

实验动物模型的肺和结肠肿瘤引发剂。

pictograms

GHS02,GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H225,H301 + H311 + H331,H314,H335,H350,H411

pcodes

P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

14.0 °F - closed cup

flash_point_c

-10 °C - closed cup

ppe

Faceshields, Gloves, Goggles

法规信息

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Cancer research has revealed that the classical model of carcinogenesis, a three step process consisting of initiation, promotion, and progression, is not complete.

On the reaction of β-naphthol with N, N-dimethylhydrazine-a new radical amination process

Barton DHR, et al.

Tetrahedron Letters, 24(15), 1601-1604 (1983)

A mild and efficient method for the preparation of anilines from nitroarenes

Boothroyd SR and Kerr MA

Tetrahedron Letters, 36(14), 2411-2414 (1995)

Decrypting the Molecular Mechanistic Pathways Delineating the Chemotherapeutic Potential of Ruthenium-Phloretin Complex in Colon Carcinoma Correlated with the Oxidative Status and Increased Apoptotic Events.

Guoguo Jin et al.

Oxidative medicine and cellular longevity, 2020, 7690845-7690845 (2020-06-23)

To explore fresh strategies in colorectal cancer (CRC) chemotherapy, we evaluated the capability of the ruthenium-phloretin complex in exterminating colon cancer by effectively addressing multiple apoptotic mechanisms on HT-29 cancer cells together with an animal model of colorectal cancer activated

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货号	GTIN
D161608-500G	04061836830656
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D161608-100G	04061836830649