D161608
N,N-二甲基肼
98%
别名:
1,1-二甲基肼, 不对称二甲肼
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线性分子式:
(CH3)2NNH2
化学文摘社编号:
分子量:
60.10
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-316-0
Beilstein/REAXYS Number:
605261
MDL number:
Assay:
98%
Form:
liquid
InChI key
RHUYHJGZWVXEHW-UHFFFAOYSA-N
InChI
1S/C2H8N2/c1-4(2)3/h3H2,1-2H3
SMILES string
CN(C)N
vapor density
1.94 (vs air)
vapor pressure
103 mmHg ( 20 °C)
assay
98%
form
liquid
autoignition temp.
478 °F
expl. lim.
95 %
refractive index
n20/D 1.4075 (lit.)
bp
60-62 °C (lit.)
density
0.79 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Application
N，N-二甲基肼可与以下物质反应：
N，N-二甲基肼与六水合氯化铁形成一种有效的还原系统，用于：
- β-萘酚，经自由基胺化形成1-氨基-2-萘酚。
- 2-氯-和2，2-二氯-（溴）乙烯基酮，通过区域选择性杂环化形成3-取代的1-甲基（5-卤代）吡唑。
- 端炔，在TpRuCl（PPh3）2 （Tp =三（吡唑基）硼酸酯）的存在下形成腈。
N，N-二甲基肼与六水合氯化铁形成一种有效的还原系统，用于：
- 通过相应硝基醛的还原环化合成DNA结合吡咯并[2,1-c][1,4]苯并二氮杂（PBD）亚胺。
- 将各种硝基芳烃和叠氮基化合物分别转化为相应的苯胺和氨基化合物。
Biochem/physiol Actions
实验动物模型的肺和结肠肿瘤引发剂。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
14.0 °F - closed cup
flash_point_c
-10 °C - closed cup
ppe
Faceshields, Gloves, Goggles
法规信息
新产品
此项目有
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A mild and efficient method for the preparation of anilines from nitroarenes
Boothroyd SR and Kerr MA
Tetrahedron Letters, 36(14), 2411-2414 (1995)
On the reaction of β-naphthol with N, N-dimethylhydrazine-a new radical amination process
Barton DHR, et al.
Tetrahedron Letters, 24(15), 1601-1604 (1983)
Guoguo Jin et al.
Oxidative medicine and cellular longevity, 2020, 7690845-7690845 (2020-06-23)
To explore fresh strategies in colorectal cancer (CRC) chemotherapy, we evaluated the capability of the ruthenium-phloretin complex in exterminating colon cancer by effectively addressing multiple apoptotic mechanisms on HT-29 cancer cells together with an animal model of colorectal cancer activated
B Toth
Cancer research, 35(12), 3693-3697 (1975-12-01)
The various synthetic substituted hydrazines, which cause tumors in animals, are briefly enumerated. To date, 19 of them have proved to be tumorigenic in animals. A number of these chemicals are found today in the environment, in industry, in agriculture
商品
Cancer research has revealed that the classical model of carcinogenesis, a three step process consisting of initiation, promotion, and progression, is not complete.
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