M56557
4-甲基吗啉
ReagentPlus®, 99%
别名:
N -甲基吗啉, NMM
蒸汽密度
>1 (vs air)
质量水平
蒸汽压
18 mmHg ( 20 °C)
产品线
ReagentPlus®
方案
99%
表单
liquid
dilution
(for general lab use)
折射率
n20/D 1.435 (lit.)
沸点
115-116 °C/750 mmHg (lit.)
mp
−66 °C (lit.)
密度
0.92 g/mL at 25 °C (lit.)
SMILES字符串
CN1CCOCC1
InChI
1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3
InChI key
SJRJJKPEHAURKC-UHFFFAOYSA-N
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一般描述
4-甲基吗啉，又称N-甲基吗啉，是一种环状叔胺，常用作高值溶剂和纤维素用精细化学品。
应用
4-甲基吗啉可用于通过与溴丁烷反应合成 N -丁基- N -甲基吗啉溴。
4-甲基吗啉可用于：
- 合成N-甲基吗啉-N-氧化物(NMMO)
- 作为便宜有效的添加剂，用于(S)-H8-BINOL-Ti(Oi-Pr)2络合物催化的芳基醛的高度对映选择性芳基化。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险声明
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
53.6 °F - closed cup - DIN 51755 Part 1
闪点(°C)
12 °C - closed cup - DIN 51755 Part 1
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Size-controlled electrochemical synthesis of palladium nanoparticles using morpholinium ionic liquid.
Cha J H, et al.
Korean Journal of Chemical Engineering, 24(6), 1089-1094 (2007)
Benedetta Del Secco et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 18(9), 2142-2149 (2019-04-24)
Silica nanoparticles (NPs) are versatile nanomaterials, which are safe with respect to biomedical applications, and therefore are highly investigated. The advantages of NPs include their ease of preparation, inexpensive starting materials and the possibility of functionalization or loading with various
V Balachandran et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1101-1110 (2012-08-30)
The experimental FT-IR (4000-400 cm(-1)) and FT-Raman (3500-100 cm(-1)) spectra of 4-Methylmorpholine were recorded. The observed bands were interpreted with the aid of normal coordinate analysis and force field calculations based on density functional theory (DFT) using B3LYP functional theory
K Sitarek
Teratogenesis, carcinogenesis, and mutagenesis, 19(6), 369-376 (1999-12-10)
N-methylmorpholine, which is used as a catalyst in polyurethane foams producing, in solvents, stabilizing agents, and corrosion inhibitors, was administered to female rats by gavage at 100, 200, 600, and 900 mg/kg during organogenesis. It did not exhibit selective toxicity
L Hansén et al.
Scandinavian journal of work, environment & health, 12(1), 66-69 (1986-02-01)
The N-methylmorpholine levels in workroom air in a polyurethane foam factory were determined by two methods in which midget impinger flasks were used for sampling. The analyses were performed by gas chromatography and isotachophoresis. The values obtained by the gas
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