M72803
2-甲基哌啶
98%
别名:
α-甲基哌啶, 2-哌可啉, NSC 31047, NSC 462
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关于此项目
经验公式（希尔记法）:
C6H13N
化学文摘社编号:
分子量:
99.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-642-1
Beilstein/REAXYS Number:
79804
MDL number:
Assay:
98%
Form:
liquid
InChI key
NNWUEBIEOFQMSS-UHFFFAOYSA-N
InChI
1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3
SMILES string
CC1CCCCN1
assay
98%
form
liquid
refractive index
n20/D 1.445 (lit.)
bp
118-119 °C/753 mmHg (lit.)
density
0.844 g/mL at 25 °C (lit.)
Application
通过定向过渡金属催化的sp3 C-H活化进行哌啶C-2芳基化的反应物
用于合成以下物质的反应物：
用于合成以下物质的反应物：
- 通过两步[5+2]成环反应合成氮杂环庚
- 2-氨基苯并恶唑
- 不对称取代脲
- 促肾上腺皮质激素释放因子受体1型拮抗剂
- 具有抗肿瘤活性的吉非替尼类似物
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
50.0 °F - closed cup
flash_point_c
10 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
C-2 arylation of piperidines through directed transition-metal-catalyzed sp3 C-H activation.
Hana Prokopcová et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(44), 13063-13067 (2010-10-29)
Dmitry Zuev et al.
Bioorganic & medicinal chemistry letters, 20(12), 3669-3674 (2010-05-18)
A novel series of [6-chloro-2-trifluoromethyl-7-aryl-7H-imidazo[1,2-a]imidazol-3-ylmethyl]-dialkylamines was discovered as potent CRF(1)R antagonists. The optimization of binding affinity in the series by the parallel reaction approach is discussed herein.
Li Cui et al.
Chemical communications (Cambridge, England), 46(19), 3351-3353 (2010-05-06)
A surprisingly efficient synthesis of azepan-4-ones via a two-step [5 + 2] annulation is developed. This reaction involves a key gold catalysis and shows generally high regioselectivities and good to excellent diastereoselectivities.
Xiaoqing Wu et al.
Bioorganic & medicinal chemistry, 18(11), 3812-3822 (2010-05-15)
There is an urgent need to design and develop new and more potent EGFR inhibitors with improved anti-tumor activity. Here we describe the design and synthesis of two series of 4-benzothienyl amino quinazolines as new analogues of the EGFR inhibitor
Christopher L Cioffi et al.
The Journal of organic chemistry, 75(22), 7942-7945 (2010-10-27)
The synthesis of 2-aminobenzoxazoles can be readily achieved by two versatile, one-pot procedures utilizing commercially available tetramethyl orthocarbonate or 1,1-dichlorodiphenoxymethane, an amine, and an optionally substituted 2-aminophenol. The reactions were conducted under mild conditions and provided 2-aminobenzoxazoles in modest to
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