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Merck
CN

M81802

二甲基亚砜

≥99%

别名:

DMSO, 甲基亚砜

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线性分子式:
(CH3)2SO
化学文摘社编号:
分子量:
78.13
EC Number:
200-664-3
MDL number:
Beilstein/REAXYS Number:
506008
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InChI

1S/C2H6OS/c1-4(2)3/h1-2H3

InChI key

IAZDPXIOMUYVGZ-UHFFFAOYSA-N

SMILES string

CS(C)=O

vapor pressure

0.42 mmHg ( 20 °C)

assay

≥99%

autoignition temp.

573 °F

expl. lim.

42 %, 63 °F

availability

available only in EU

density

1.10 g/mL (lit.)

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General description

Dimethyl Sulfoxide (DMSO) is a polar aprotic solvent that is generally used as a reaction medium and reagent in organic reactions.

Application

Dimethyl Sulfoxide can be used as:      
  • An oxidant for the conversion of isonitriles into isocyanates.
  •  A solvent in polymerase chain reaction.       
  • A cryoprotectant for the preservation of cells, tissues and organs.        
  • An oxidant in Swern oxidation, that can be activated by oxalyl chloride and used in the oxidation of long-chain alcohols to carbonyls.        
  • Solvent/oxidant in the α-hydroxylation of ketones in the presence of NBS/I2 catalyst.

Disclaimer

在室温下容易过冷并缓慢重融。 固化产品可以通过加热至室温来重新液化,而不会损害产品。

存储类别

10 - Combustible liquids

wgk

WGK 1

flash_point_f

188.6 °F - closed cup

flash_point_c

87 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Yu-Feng Liang et al.
Organic letters, 17(4), 876-879 (2015-02-05)
An efficient method for the direct preparation of high synthetic valuable α-hydroxycarbonyls is described. The simple and readily available I2 or NBS was used as catalyst. DMSO acts as the oxidant, oxygen source, and solvent. A diverse range of tertiary
Pre-PCR processing
Raadstrom P, et al.
Molecular Biotechnology, 26(2), 133-146 (2004)
Oxidation of Alcohols to Carbonyl Compounds via Alkoxysulfonium Ylides: The M offatt, S wern, and Related Oxidations
Tidwell TT
Organic Reactions, 39, 297-555 (2004)
L E McGann et al.
Cryobiology, 24(1), 11-16 (1987-02-01)
Preservation of cells and tissues at low temperatures requires the presence of effective cryoprotectants with low toxicity to which cells are relatively permeable. Two similar compounds, dimethyl sulfoxide (DMSO) and dimethyl sulfone (DMSO2), exhibit both features for cryoprotectants, yet DMSO
Kara Capriotti et al.
The Journal of clinical and aesthetic dermatology, 5(9), 24-26 (2012-10-11)
Dimethyl sulfoxide is a colorless liquid derived as a by-product from wood pulp in the production of paper. This colorless liquid found immediate application as a polar, aprotic solvent miscible with water and able to dissolve an enormous catalog of

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