Merck
CN

P11255

Sigma-Aldrich

PTCDA

97%

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别名:
3,4,9,10-苝四甲酸二酐, Pigment Red 224
Empirical Formula (Hill Notation):
C24H8O6
CAS号:
分子量:
392.32
Beilstein:
57831
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.23

描述

Band gap: 2.1 eV

质量水平

检测方案

97%

形式

powder

mp

>300 °C

轨道能量

HOMO -6.8 eV 
LUMO -4.7 eV 

OPV设备性能

ITO/CuPc/PTCDA/In

  • Short-circuit current density (Jsc): 2 mA/cm2
  • Open-circuit voltage (Voc): 0.55 V
  • Fill Factor (FF): 0.35
  • Power Conversion Efficiency (PCE): 1.8 %

半导体性质

N-type (mobility=10−4 cm2/V·s)

InChI

1S/C24H8O6/c25-21-13-5-1-9-10-2-6-15-20-16(24(28)30-23(15)27)8-4-12(18(10)20)11-3-7-14(22(26)29-21)19(13)17(9)11/h1-8H

InChI key

CLYVDMAATCIVBF-UHFFFAOYSA-N

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412287N818932353
PTCDA 97%

Sigma-Aldrich

P11255

PTCDA

Pyromellitic dianhydride 97%

Sigma-Aldrich

412287

均苯四甲酸酐

1,4,5,8-Naphthalenetetracarboxylic dianhydride

Sigma-Aldrich

N818

1,4,5,8-萘四甲酸酐

PTCDI

Sigma-Aldrich

932353

PTCDI

mp

>300 °C

mp

283-286 °C (lit.)

mp

>300 °C (lit.)

mp

-

description

Band gap: 2.1 eV

description

-

description

-

description

-

assay

97%

assay

97%

assay

-

assay

-

orbital energy

HOMO -6.8 eV 

orbital energy

-

orbital energy

-

orbital energy

-

OPV device performance

ITO/CuPc/PTCDA/In

  • Short-circuit current density (Jsc): 2 mA/cm2
  • Open-circuit voltage (Voc): 0.55 V
  • Fill Factor (FF): 0.35
  • Power Conversion Efficiency (PCE): 1.8 %

OPV device performance

-

OPV device performance

-

OPV device performance

-

一般描述

3,4,9,10-四羧酸二酐苝(PTCDA)是苝衍生物,可形成高度结晶的薄膜和染料,用于大多数电子和光电子应用。由于其分子间距离短,导致π-π共轭,因此具有较高的电子迁移率。

应用

PTCDA与基于聚丙二醇(PPG)二胺的缩聚反应可用于开发苝二酰亚胺,而苝二酰亚胺有潜力作为有机光伏领域的n型半导体。PTCDA可作为吸光单体,用于制造bichromophobic光采集天线系统。也可以用于制备3、4、9、10-苝四羧酸-芳族荧光团染料,在不同底物上实现高度可逆的荧光转换。

储存分类代码

11 - Combustible Solids

WGK

WGK 1

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Ling Fan et al.
Advanced materials (Deerfield Beach, Fla.), 30(20), e1800804-e1800804 (2018-04-01)
A low cost nonaqueous potassium-based battery-supercapacitor hybrid device (BSH) is successfully established for the first time with soft carbon as the anode, commercialized activated carbon as the cathode, and potassium bis(fluoro-slufonyl)imide in dimethyl ether as the electrolyte. This BSH reconciles
Tunable and highly efficient light-harvesting antenna systems based on 1, 7-perylene-3, 4, 9, 10-tetracarboxylic acid derivatives.
Dubey RK, et al.
Chemical Science, 7(6), 3517-3532 (2016)
S J Richard Prabakar et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(24), 1902129-1902129 (2020-01-01)
Herein, graphite is proposed as a reliable Ca2+-intercalation anode in tetraglyme (G4). When charged (reduced), graphite accommodates solvated Ca2+-ions (Ca-G4) and delivers a reversible capacity of 62 mAh g-1 that signifies the formation of a ternary intercalation compound, Ca-G4·C72. Mass/volume
Xiaoqing Chen et al.
Nano letters, 17(10), 6391-6396 (2017-09-07)
Interfacing light-sensitive semiconductors with graphene can afford high-gain phototransistors by the multiplication effect of carriers in the semiconductor layer. So far, most devices consist of one semiconductor light-absorbing layer, where the lack of internal built-in field can strongly reduce the
Morphology, structure and photophysics of thin films of perylene-3, 4, 9, 10-tetracarboxylic dianhydride.
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