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Merck
CN

P11255

PTCDA

97%

别名:

3,4,9,10-苝四甲酸二酐, Pigment Red 224

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关于此项目

经验公式(希尔记法):
C24H8O6
化学文摘社编号:
分子量:
392.32
PubChem Substance ID:
UNSPSC Code:
12352103
NACRES:
NA.23
EC Number:
204-905-3
MDL number:
Beilstein/REAXYS Number:
57831
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SMILES string

O1C(=O)c2c3c4c(c5c6c(c4cc2)ccc7c6c(cc5)C(=O)OC7=O)ccc3C1=O

InChI

1S/C24H8O6/c25-21-13-5-1-9-10-2-6-15-20-16(24(28)30-23(15)27)8-4-12(18(10)20)11-3-7-14(22(26)29-21)19(13)17(9)11/h1-8H

InChI key

CLYVDMAATCIVBF-UHFFFAOYSA-N

description

Band gap: 2.1 eV

assay

97%

form

powder

mp

>300 °C

orbital energy

HOMO -6.8 eV , LUMO -4.7 eV 

OPV device performance

ITO/CuPc/PTCDA/In

  • Short-circuit current density (Jsc): 2 mA/cm2
  • Open-circuit voltage (Voc): 0.55 V
  • Fill Factor (FF): 0.35
  • Power Conversion Efficiency (PCE): 1.8 %

semiconductor properties

N-type (mobility=10−4 cm2/V·s)

Quality Level

General description

3,4,9,10-四羧酸二酐苝(PTCDA)是苝衍生物,可形成高度结晶的薄膜和染料,用于大多数电子和光电子应用。由于其分子间距离短,导致π-π共轭,因此具有较高的电子迁移率。

Application

PTCDA与基于聚丙二醇(PPG)二胺的缩聚反应可用于开发苝二酰亚胺,而苝二酰亚胺有潜力作为有机光伏领域的n型半导体。PTCDA可作为吸光单体,用于制造bichromophobic光采集天线系统。也可以用于制备3、4、9、10-苝四羧酸-芳族荧光团染料,在不同底物上实现高度可逆的荧光转换。

存储类别

11 - Combustible Solids

wgk

WGK 1

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Sylvie Rangan et al.
The journal of physical chemistry. B, 122(2), 534-542 (2017-06-21)
The adsorption geometry and energy alignment at the PTCDA/TiO
Zhixuan Wei et al.
Nature communications, 10(1), 3227-3227 (2019-07-22)
The interactions between charge carriers and electrode structures represent one of the most important considerations in the search for new energy storage devices. Currently, ionic bonding dominates the battery chemistry. Here we report the reversible insertion of a large molecular
Fanfan Du et al.
Cellular and molecular bioengineering, 10(5), 357-370 (2017-10-11)
Intracellular delivery is a key step for many applications in medicine and for investigations into cellular function. This is particularly true for immunotherapy, which often requires controlled delivery of antigen and adjuvants to the cytoplasm of immune cells. Due to
Pavel Kocán et al.
Physical chemistry chemical physics : PCCP, 21(18), 9504-9511 (2019-04-25)
Realization of future hybrid electronic devices combining organic and inorganic semiconductors requires a well-defined interface between both components. Such an interface can be formed generally by self-ordering of organic molecules on inorganic substrates, which is usually hindered by strong covalent
Morphology, structure and photophysics of thin films of perylene-3, 4, 9, 10-tetracarboxylic dianhydride.
Heutz S, et al.
Organic Electronics, 3(3-4), 119-127 (2002)

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