T50202
三丁基氯化锡
96%
别名:
TBTC, 氯化三丁基锡
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关于此项目
线性分子式:
[CH3(CH2)3]3SnCl
化学文摘社编号:
分子量:
325.51
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
215-958-7
Beilstein/REAXYS Number:
3535715
MDL number:
Assay:
96%
InChI key
GCTFWCDSFPMHHS-UHFFFAOYSA-M
InChI
1S/3C4H9.ClH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1
SMILES string
CCCC[Sn](Cl)(CCCC)CCCC
vapor pressure
<0.01 mmHg ( 20 °C)
assay
96%
Quality Level
bp
171-173 °C/25 mmHg (lit.)
density
1.2 g/mL at 25 °C (lit.)
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Application
Tributyltin chloride (Bu3SnCl or tri-n-butylstannane) is an organotin compound that can be used as a reagent for:
- The synthesis of fluorinated stannanes by reacting with fluorinated alkyl, aryl or vinyl halides using Zn or Cd catalyst via Barbier-type reaction.
- The preparation of γ-hydroxyvinylstannanes, and indol-2-yltributylstannane.
- The conversion of organozirconiums to organostannanes.
signalword
Danger
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1B - STOT RE 1
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
226.4 °F - closed cup
flash_point_c
108 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Rita Jordão et al.
Environmental health perspectives, 123(8), 813-819 (2015-03-25)
The analysis of obesogenic effects in invertebrates is limited by our poor knowledge of the regulatory pathways of lipid metabolism. Recent data from the crustacean Daphnia magna points to three signaling hormonal pathways related to the molting and reproductive cycles
Transmetalation from zirconium to tin: A facile preparation of organostannanes from organozirconiums
Kim S and Kim KH
Tetrahedron Letters, 36(21), 3725-3728 (1995)
Fluorinated stannanes: Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium
Burton DJ and Jairaj V
Journal of Fluorine Chemistry, 126(5), 797-801 (2005)
A Route to the Preparation of γ -Hydroxyvinylstannanes
Lautens M and Huboux AH
Tetrahedron Letters, 31(22), 3105-3108 (1990)
Julia F P de Araújo et al.
Toxicology letters, 295, 99-114 (2018-06-18)
Tributyltin chloride (TBT) is an obesogen associated with various metabolic and reproductive dysfunctions after in utero exposure. However, few studies have evaluated TBT's obesogenic effect on adult ovaries. In this study, we assessed whether TBT's obesogenic effects resulted in adult
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