04124
1-(3-氰丙基)-3-甲基氯化咪唑鎓
Task Specific Ionic Liquid (TSIL), ≥98.5% (T)
别名:
1-甲基-3-(3-氰丙基)氯化咪唑鎓
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关于此项目
经验公式（希尔记法）:
C8H12ClN3
化学文摘社编号:
分子量:
185.65
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
InChI
1S/C8H12N3.ClH/c1-10-6-7-11(8-10)5-3-2-4-9;/h6-8H,2-3,5H2,1H3;1H/q+1;/p-1
SMILES string
[Cl-].C[n+]1ccn(CCCC#N)c1
InChI key
HGPSWUJKMXIBKA-UHFFFAOYSA-M
assay
≥98.5% (T), ≥98.5% (elemental analysis, N)
form
powder
impurities
≤0.5% water
Quality Level
General description
Suzuki 和 Stille 偶联反应中具有优异特性的腈官能化离子液体。
Application
1-(3-Cyanopropyl)-3-methylimidazolium chloride can be used:
- To prepare ionic polymers stabilized with palladium nanoparticle catalysts, which are applicable in the hydrogenation of alkenes and arenes.
- As a solvent in the synthesis of substituted 4-arylthio-1,2-oxazoles by reacting different aryl iodides with acetylenic oximes in the presence of Pd-NHC catalyst.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Recent advances in sulfuration chemistry enabled by bunte salts
Wang M, et al.
Aldrichimica Acta, 53(1), 19-19 (2020)
Aqueous-phase hydrogenation of alkenes and arenes: The growing role of nanoscale catalysts
Bulut S, et al.
Catalysis Today, 247, 96-103 (2015)
Dongbin Zhao et al.
Journal of the American Chemical Society, 126(48), 15876-15882 (2004-12-02)
A series of relatively low-cost ionic liquids, based on the N-butyronitrile pyridinium cation [C(3)CNpy](+), designed to improve catalyst retention, have been prepared and evaluated in Suzuki and Stille coupling reactions. Depending on the nature of the anion, these salts react
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