30899
1,2,3-三氯丙烷
certified reference material, TraceCERT®
别名:
Trichlorohydrin, 三氯丙烷
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线性分子式:
CH2ClCHClCH2Cl
化学文摘社编号:
分子量:
147.43
EC Number:
202-486-1
UNSPSC Code:
41116107
PubChem Substance ID:
Beilstein/REAXYS Number:
1732068
MDL number:
InChI
1S/C3H5Cl3/c4-1-3(6)2-5/h3H,1-2H2
InChI key
CFXQEHVMCRXUSD-UHFFFAOYSA-N
SMILES string
ClCC(Cl)CCl
grade
certified reference material, TraceCERT®
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
bp
156 °C (lit.)
mp
−14 °C (lit.)
density
1.387 g/mL at 25 °C (lit.)
application(s)
cleaning products
cosmetics
food and beverages
personal care
format
neat
storage temp.
2-8°C
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com.
Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - STOT RE 1 Inhalation
target_organs
Kidney,Liver,Mucous membranes
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
165.2 °F - DIN 51758
flash_point_c
74 °C - DIN 51758
法规信息
新产品
此项目有
Successful therapy with hemoperfusion and plasma exchange in acute 1,2,3-trichloropropane poisoning.
P Liu et al.
Human & experimental toxicology, 31(5), 523-527 (2011-11-03)
1,2,3-trichloropropane (1,2,3-TCP) is commonly used as an intermediate in pesticide and an industrial specialty solvent. Acute 1,2,3-TCP poisoning is rare but a medical emergency. Sporadic cases of toxic hepatic injury from 1,2,3-TCP in humans have been reported. Liver is a
Alena Stsiapanava et al.
Acta crystallographica. Section F, Structural biology and crystallization communications, 67(Pt 2), 253-257 (2011-02-09)
Haloalkane dehalogenases make up an important class of hydrolytic enzymes which catalyse the cleavage of carbon-halogen bonds in halogenated aliphatic compounds. There is growing interest in these enzymes owing to their potential use in environmental and industrial applications. The haloalkane
Martina Pavlova et al.
Nature chemical biology, 5(10), 727-733 (2009-08-25)
Engineering enzymes to degrade anthropogenic compounds efficiently is challenging. We obtained Rhodococcus rhodochrous haloalkane dehalogenase mutants with up to 32-fold higher activity than wild type toward the toxic, recalcitrant anthropogenic compound 1,2,3-trichloropropane (TCP) using a new strategy. We identified key
Marta Monincová et al.
Applied and environmental microbiology, 73(6), 2005-2008 (2007-01-30)
1,2,3-Trichloropropane (TCP) is a highly toxic and recalcitrant compound. Haloalkane dehalogenases are bacterial enzymes that catalyze the cleavage of a carbon-halogen bond in a wide range of organic halogenated compounds. Haloalkane dehalogenase LinB from Sphingobium japonicum UT26 has, for a
Pavel Banás et al.
Journal of computer-aided molecular design, 20(6), 375-383 (2006-10-04)
1,2,3-Trichloropropane (TCP) is a highly toxic, recalcitrant byproduct of epichlorohydrin manufacture. Haloalkane dehalogenase (DhaA) from Rhodococcus sp. hydrolyses the carbon-halogen bond in various halogenated compounds including TCP, but with low efficiency (k (cat)/K (m )= 36 s(-1) M(-1)). A Cys176Tyr-DhaA
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