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Merck
CN

310328

碳酸丙烯酯

anhydrous, 99.7%

别名:

1,2-丙二醇碳酸酯, 4-甲基-1,3-二氧戊环-2-酮

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关于此项目

经验公式（希尔记法）:
C4H6O3
化学文摘社编号:
108-32-7
分子量:
102.09
UNSPSC Code:
12352005
NACRES:
NA.21
PubChem Substance ID:
57648504
EC Number:
203-572-1
Beilstein/REAXYS Number:
107913
MDL number:
MFCD00005385
Grade:
anhydrous
Assay:
99.7%
Bp:
240 °C (lit.)
Vapor pressure:
0.13 mmHg ( 20 °C)
0.98 mmHg ( 50 °C)

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产品名称

碳酸丙烯酯, anhydrous, 99.7%

InChI key

RUOJZAUFBMNUDX-UHFFFAOYSA-N

InChI

1S/C4H6O3/c1-3-2-6-4(5)7-3/h3H,2H2,1H3

SMILES string

CC1COC(=O)O1

grade

anhydrous

vapor pressure

0.13 mmHg ( 20 °C)
0.98 mmHg ( 50 °C)

assay

99.7%

form

liquid

autoignition temp.

851 °F

expl. lim.

14.3 %

impurities

<0.002% water
<0.005% water (100 mL pkg)

refractive index

n20/D 1.421 (lit.)

pH

7 (20 °C, 200 g/L)

bp

240 °C (lit.)

mp

−55 °C (lit.)

density

1.204 g/mL at 25 °C (lit.)

Quality Level

100

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相关类别

Application

碳酸丙烯酯可用作非官能化烯烃的不对称加氢反应的溶剂。

General description

碳酸丙烯酯可由环氧丙烷和CO2合成。光学活性形式的碳酸丙烯酯可通过CO2 与外消旋环氧化物的反应进行制备。在锂电池的石墨电极上分解碳酸丙烯酯，可形成嵌锂化合物。
碳酸丙烯酯是一种环状碳酸酯，通常被用作有机合成的溶剂和反应性中间体。由于碳酸丙烯酯具有低蒸气压、高介电常数和高化学稳定性，它被认为是一种潜在的电化学溶剂。

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

存储类别

10 - Combustible liquids

wgk

WGK 1

flash_point_f

269.6 °F - closed cup

flash_point_c

132 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBT2619
SHBT0879
SHBS9412
SHBS5752
SHBS0083

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Xiao-Bing Lu et al.
Journal of the American Chemical Society, 126(12), 3732-3733 (2004-03-25)
This communication describes a convenient route to optically active propylene carbonate by a catalytic kinetic resolution process resulting from the coupling reaction of CO2 and racemic epoxides using simple chiral SalenCo(III)/quaternary ammonium halide catalyst systems.
Michael L Aubrey et al.
Nature materials, 17(7), 625-632 (2018-06-06)
Conductive metal-organic frameworks are an emerging class of three-dimensional architectures with degrees of modularity, synthetic flexibility and structural predictability that are unprecedented in other porous materials. However, engendering long-range charge delocalization and establishing synthetic strategies that are broadly applicable to
The cathodic decomposition of propylene carbonate in lithium batteries.
Arakawa M and Yamaki JI.
Journal of Electroanalytical Chemistry, 219(1-2), 273-280 (1987)
Vincenza Modafferi et al.
Nanomaterials (Basel, Switzerland), 10(8) (2020-08-19)
The effect of the type of dopant (titanium and manganese) and of the reduced graphene oxide content (rGO, 30 or 50 wt %) of the α-Fe2O3@rGO nanocomposites on their microstructural properties and electrochemical performance was investigated. Nanostructured composites were synthesized
Propylene carbonate: a versatile solvent for electrochemistry and EPR.
Nelson RF & Adams RN.
J. Electroanal. Chem. Interfac. Electrochem., 13(1), 184-187 (1967)
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