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Merck
CN

31288

硝酸铜 半(五水合物)

puriss. p.a., ACS reagent, 99-102%

别名:

Cupric nitrate 半(五水合物)

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关于此项目

线性分子式:
Cu(NO3)2 · 2.5H2O
化学文摘社编号:
19004-19-4
分子量:
232.59
EC Number:
221-838-5
UNSPSC Code:
12352300
MDL number:
MFCD02253001

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InChI key

IZDJJEMZQZQQQQ-UHFFFAOYSA-N

InChI

1S/2Cu.4NO3.5H2O/c;;4*2-1(3)4;;;;;/h;;;;;;5*1H2/q2*+2;4*-1;;;;;

SMILES string

O.O.O.O.O.[Cu++].[Cu++].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

grade

ACS reagent, puriss. p.a.

assay

99-102%

impurities

≤0.01% insoluble matter in dilute HNO3

pH

3.5-4.5 (20 °C, 5%)

anion traces

chloride (Cl-): ≤10 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg, Fe: ≤20 mg/kg, K: ≤100 mg/kg, Mg: ≤10 mg/kg, Na: ≤100 mg/kg, Ni: ≤20 mg/kg, Pb: ≤10 mg/kg, Zn: ≤10 mg/kg

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General description

Copper(II) nitrate hemi(pentahydrate) is an inorganic copper salt.

Application

Copper(II) nitrate hemi(pentahydrate) may be employed as copper precursor for the preparation of thin film of Cu2ZnSnS4 (CZTS). It may be used in the preparation of 4-methoxypyridine-(pyridine-2,6-dicarboxylato-N,O,O′) copper (II) and in the synthesis of coordination pillared-layer frameworks (CPLs), particularly CPL-1, via mechanochemical method.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - Ox. Sol. 1 - Skin Corr. 1B

存储类别

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number
23310
03160
62930
51590
03130

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Non-vacuum processed Cu2 ZnSnS4 thin films: influence of copper precursor on structural, optical and morphological properties.
Aslan F and Tumbul A.
J. Alloy Compounds, 612, 1-4 (2014)
4-Methoxypyridine-(pyridine-2, 6-dicarboxylato-N, O, O') copper (II).
Perry JJ, et al.
Journal of Chemical Crystallography, 34(12), 877-881 (2004)
Hirotoshi Sakamoto et al.
Dalton transactions (Cambridge, England : 2003), 41(14), 3956-3961 (2012-01-21)
A detailed investigation into the mechanochemical synthesis of coordination pillared-layer frameworks (CPLs), particularly CPL-1, was carried out. In the case of CPL-1, a two-step reaction was observed (from the starting reactants to the final product). In the conventional solution process
Derak J James et al.
ACS applied materials & interfaces, 7(42), 23623-23632 (2015-10-20)
Derivatives of synthetic tetrahedrite, Cu12Sb4S13, are receiving increasing attention in the thermoelectric community due to their exploitation of plentiful, relatively nontoxic elements, combined with a thermoelectric performance that rivals that of PbTe-based compounds. However, traditional synthetic methods require weeks of

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