32208
二甘醇二甲醚
puriss., absolute, over molecular sieve (H2O ≤0.005%), ≥99.5% (GC)
别名:
2-甲氧基乙醚, ‘二甘醇’, 二甲基二甘醇, 双(2-甲氧基乙基)醚
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关于此项目
线性分子式:
(CH3OCH2CH2)2O
化学文摘社编号:
分子量:
134.17
EC Number:
203-924-4
UNSPSC Code:
12352112
PubChem Substance ID:
Beilstein/REAXYS Number:
1736101
MDL number:
vapor density
4.6 (vs air)
vapor pressure
3 mmHg ( 20 °C)
grade
absolute, puriss.
assay
≥99.5% (GC)
autoignition temp.
370 °F
quality
over molecular sieve (H2O ≤0.005%)
expl. lim.
17.4 %
refractive index
n20/D 1.408
bp
162 °C (lit.)
mp
−64 °C (lit.)
density
0.944 g/mL at 20 °C (lit.), 0.939 g/mL at 25 °C (lit.)
SMILES string
COCCOCCOC
InChI
1S/C6H14O3/c1-7-3-5-9-6-4-8-2/h3-6H2,1-2H3
InChI key
SBZXBUIDTXKZTM-UHFFFAOYSA-N
General description
Diethylene glycol dimethyl ether (diglyme), a less volatile liquid, is widely employed as an anhydrous solvent. Various physical properties (density, refractive index, speed of sound and shear viscosity) of its mixtures with ethyl acetate, methyl benzoate, ethyl benzoate or diethyl succinate have been evaluated at various temperature ranges.
Application
Diethylene glycol dimethyl ether (diglyme) was used for the immobilization of biological compounds onto a gold surface via dextran chemistry. It was employed as solvent for the functionalization of carbon nano fibers, via the Diels Alder reaction. It may be used in the preparation of linear poly(glycidol) (PG), via anionic polymerization. It may be used as solvent for the extraction of tattoo colorants and their degradation products from various media by recovery experiments and HPLC-diode array detector technology.
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Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Repr. 1B
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
134.6 °F - closed cup
flash_point_c
57 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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Eva Engel et al.
Analytical chemistry, 78(18), 6440-6447 (2006-09-15)
Tattooing is a widespread process of puncturing pigments into skin, whereas the resulting concentration inside the skin remains unknown. Many tattoo colorants are organic pigments, such as azo pigments, manufactured for other uses. To remove tattoos from skin, laser pulses
Qian Cheng et al.
Biomaterials, 30(25), 4203-4210 (2009-05-30)
Polyethylene glycol (PEG)-like films were grafted onto various substrates by plasma polymerization of diethylene glycol dimethyl ether (diglyme). Low-power diglyme plasma conditions yielded PEG-like films exhibiting nonfouling behavior, as evidenced by the significant decrease in protein adsorption and cell attachment
Kikuko Hayamizu et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 167(2), 328-333 (2004-03-26)
Pulsed gradient spin-echo (PGSE) NMR measurements of the self-diffusion coefficients of low viscosity liquids are greatly hampered by the effects of convection especially away from ambient temperature. Here we report on a new NMR tube designed to minimize the deleterious