32766
环磺酮
PESTANAL®, analytical standard
别名:
2-{2-氯-4-(甲磺酰)-3-[(2,2,2-三氟乙氧基)甲基]苯甲酰基}-1,3-环己二酮, 2-{2-氯-4-甲磺酰基-3-[(2,2,2-三氟乙氧基)甲基]苯甲酰基}环己烷-1,3-二酮
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关于此项目
经验公式（希尔记法）:
C17H16ClF3O6S
CAS Number:
分子量:
440.82
MDL编号:
UNSPSC代码:
41116107
PubChem化学物质编号:
NACRES:
NA.24
等级
analytical standard
质量水平
产品线
PESTANAL®
保质期
limited shelf life, expiry date on the label
技术
HPLC: suitable
gas chromatography (GC): suitable
应用
agriculture
environmental
包装形式
neat
SMILES字符串
CS(=O)(=O)c1ccc(c(Cl)c1COCC(F)(F)F)C(=O)C2C(=O)CCCC2=O
InChI
1S/C17H16ClF3O6S/c1-28(25,26)13-6-5-9(15(18)10(13)7-27-8-17(19,20)21)16(24)14-11(22)3-2-4-12(14)23/h5-6,14H,2-4,7-8H2,1H3
InChI key
IUQAXCIUEPFPSF-UHFFFAOYSA-N
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一般描述
环磺酮是 β-三酮类除草剂，在字段玉米出苗后早期到中期用于控制草和阔叶杂草。
应用
有关合适仪器技术的更多信息，请参考产品分析证书。如需进一步支持，请联系技术服务部门。
通过快速、简便、廉价、有效、耐用且安全的 (QuEchERS) 提取方法和分散液-液微萃取 (DLLME) 后采用高效液相色谱 (HPLC) 二极管阵列检测器 (DAD) 进行分析， 蜜蜂采用改良 QuEchERS 萃取后采用 LC 和气相色谱 (GC) 结合串联质谱 (MS/MS) 进行分析， 食品样品采用超高效液相色谱 (UHPLC) 和四极杆飞行时间质谱 (QTOFMS) 结合电喷雾离子化 进行分析，植物组织以及水样采用 DLLME、基质固相分散 (MSPD) 和固相萃取 (SPE) 结合 HPLC-DAD 进行分析，环磺酮可作为引用番茄中环磺酮测定的参考标准。
法律信息
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1 - STOT RE 2
靶器官
Eyes,Liver,Kidney
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
No data available
闪点(°C)
No data available
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Vilena Kašuba et al.
Environmental science and pollution research international, 27(2), 1800-1807 (2019-11-24)
DNA damage in the liver and kidney cells of adult male Wistar rats was studied using the comet assay after a 28-day oral administration of tembotrione at doses of 0.0007, 0.0013 and 0.7 mg/kg b.w./day [AOEL (acceptable operator exposure level)
Extraction procedures for the study of phytotoxicity and degradation processes of selected triketones in a water ecosystem.
Barchanska H, et al.
Environmental Science and Pollution Research International, 21(6), 4751-4758 (2014)
Screening of over 600 pesticides, veterinary drugs, food-packaging contaminants, mycotoxins, and other chemicals in food by ultra-high performance liquid chromatography quadrupole time-of-flight mass spectrometry (UHPLC-QTOFMS).
Perez-Ortega P, et al.
Food Analytical Methods, 10(5), 1216-1244 (2017)
Monopersulfate photocatalysis under 365 nm radiation. Direct oxidation and monopersulfate promoted photocatalysis of the herbicide tembotrione.
Solis RR, et al.
Journal of Environmental Management, 181, 385-394 (2016)
Anita Küpper et al.
Pest management science, 74(10), 2325-2334 (2017-11-07)
Resistance to the 4-hydroxyphenylpyruvate dioxygenase (HPPD)-inhibiting herbicide tembotrione in an Amaranthus palmeri population from Nebraska (NER) has previously been confirmed to be attributable to enhanced metabolism. The objective of this study was to identify and quantify the metabolites formed in
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