环磺酮

Name: 环磺酮
Brand: SIAL

PESTANAL^®, analytical standard

别名:

2-{2-氯-4-(甲磺酰)-3-[(2,2,2-三氟乙氧基)甲基]苯甲酰基}-1,3-环己二酮, 2-{2-氯-4-甲磺酰基-3-[(2,2,2-三氟乙氧基)甲基]苯甲酰基}环己烷-1,3-二酮

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关于此项目

经验公式（希尔记法）:

C₁₇H₁₆ClF₃O₆S

化学文摘社编号:

335104-84-2

分子量:

440.82

NACRES:

NA.24

PubChem Substance ID:

329754323

UNSPSC Code:

41116107

MDL number:

MFCD11840613

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产品名称

环磺酮, PESTANAL^®, analytical standard

InChI key

IUQAXCIUEPFPSF-UHFFFAOYSA-N

SMILES string

CS(=O)(=O)c1ccc(c(Cl)c1COCC(F)(F)F)C(=O)C2C(=O)CCCC2=O

InChI

1S/C17H16ClF3O6S/c1-28(25,26)13-6-5-9(15(18)10(13)7-27-8-17(19,20)21)16(24)14-11(22)3-2-4-12(14)23/h5-6,14H,2-4,7-8H2,1H3

grade

analytical standard

product line

PESTANAL^®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

有关合适仪器技术的更多信息，请参考产品分析证书。如需进一步支持，请联系技术服务部门。

通过快速、简便、廉价、有效、耐用且安全的 (QuEchERS) 提取方法和分散液-液微萃取 (DLLME) 后采用高效液相色谱 (HPLC) 二极管阵列检测器 (DAD) 进行分析，蜜蜂采用改良 QuEchERS 萃取后采用 LC 和气相色谱 (GC) 结合串联质谱 (MS/MS) 进行分析，食品样品采用超高效液相色谱 (UHPLC) 和四极杆飞行时间质谱 (QTOFMS) 结合电喷雾离子化进行分析，植物组织以及水样采用 DLLME、基质固相分散 (MSPD) 和固相萃取 (SPE) 结合 HPLC-DAD 进行分析，环磺酮可作为引用番茄中环磺酮测定的参考标准。

General description

环磺酮是 β-三酮类除草剂，在字段玉米出苗后早期到中期用于控制草和阔叶杂草。

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

GHS08,GHS07,GHS09

signalword

Warning

hcodes

H317,H361d,H373,H410

pcodes

P202 - P260 - P273 - P280 - P302 + P352 - P308 + P313

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1 - STOT RE 2

target_organs

Eyes,Liver,Kidney

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

No data available

flash_point_c

No data available

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

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Screening of over 600 pesticides, veterinary drugs, food-packaging contaminants, mycotoxins, and other chemicals in food by ultra-high performance liquid chromatography quadrupole time-of-flight mass spectrometry (UHPLC-QTOFMS).

Perez-Ortega P, et al.

Food Analytical Methods, 10(5), 1216-1244 (2017)

Extraction procedures for the study of phytotoxicity and degradation processes of selected triketones in a water ecosystem.

Barchanska H, et al.

Environmental Science and Pollution Research International, 21(6), 4751-4758 (2014)

DNA damage in kidney and parenchymal and non-parenchymal liver cells of adult Wistar rats after subchronic oral treatment with tembotrione.

Vilena Kašuba et al.

Environmental science and pollution research international, 27(2), 1800-1807 (2019-11-24)

DNA damage in the liver and kidney cells of adult male Wistar rats was studied using the comet assay after a 28-day oral administration of tembotrione at doses of 0.0007, 0.0013 and 0.7 mg/kg b.w./day [AOEL (acceptable operator exposure level)

Monopersulfate photocatalysis under 365 nm radiation. Direct oxidation and monopersulfate promoted photocatalysis of the herbicide tembotrione.

Solis RR, et al.

Journal of Environmental Management, 181, 385-394 (2016)

Analysis of pesticides in tomato combining QuEChERS and dispersive liquid-liquid microextraction followed by high-performance liquid chromatography.

Melo A, et al.

Food Analytical Methods, 6(2), 559-568 (2013)

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环磺酮

PESTANAL^®, analytical standard