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线性分子式:
CH3C6H3(NCO)2
化学文摘社编号:
分子量:
174.16
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
202-039-0
Beilstein/REAXYS Number:
2211546
MDL number:
InChI
1S/C9H6N2O2/c1-7-8(10-5-12)3-2-4-9(7)11-6-13/h2-4H,1H3
InChI key
RUELTTOHQODFPA-UHFFFAOYSA-N
SMILES string
Cc1c(cccc1N=C=O)N=C=O
grade
analytical standard
autoignition temp.
>1148 °F
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
Quality Level
bp
129-133 °C/18 mmHg (lit.)
density
1.225 g/mL at 25 °C (lit.)
application(s)
cleaning products
cosmetics
environmental
food and beverages
personal care
format
neat
storage temp.
2-8°C
General description
This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.
Find all available reference materials for compounds listed in 10/2011 here
Find all available reference materials for compounds listed in 10/2011 here
Application
2,6-TDI may be used as a reference standard for the quantification of residual 2,6-TDI in foam samples using high performance liquid chromatography coupled to coordination-ionspray tandem mass spectrometry (HPLC-CIS-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
signalword
Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 2
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
B W Day et al.
Chemical research in toxicology, 10(4), 424-431 (1997-04-01)
During our ongoing studies of the reactions of toluene diisocyanate (2,4- and 2,6-diisocyanatotoluene, TDI) in vivo, it became apparent that reactive form(s) of these diisocyanates reach(es) the circulatory system after passage through the respiratory system. Based on recent work by
A Maître et al.
International archives of occupational and environmental health, 65(2), 97-100 (1993-01-01)
The study validated the use of urinary toluene diamine (TDA) in postshift samples as an indicator of preceding 8-h exposure to toluene diisocyanate (TDI). Nine workers exposed in TDI-based polyurethane foam production were studied. Their exposure levels varied in 8-h
F M Benoit
Journal of biomedical materials research, 27(10), 1341-1348 (1993-10-01)
The release of toluene diisocyanate derivatives from polyurethane foam covers that were removed from the Même breast implant was studied. The polyurethane foam covers as retrieved from the implants were contaminated on average with 2,4- and 2,6-toluene diamine (TDA), 2,4-
Hui-Jung Yeh et al.
Journal of applied toxicology : JAT, 28(2), 189-195 (2007-06-22)
Toluene diisocyanates (TDI) are commonly used in polyurethane (PU)-related products. TDIs have been documented as the leading cause of occupational asthma. Skin exposure to TDI in the workplace is common. However, no studies in the literature have investigated the exact
Justin M Hettick et al.
Analytical biochemistry, 414(2), 232-238 (2011-04-05)
Diisocyanates are highly reactive chemical compounds widely used in the manufacture of polyurethanes. Although diisocyanates have been identified as causative agents of allergic respiratory diseases, the specific mechanism by which these diseases occur is largely unknown. To better understand the
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