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经验公式(希尔记法):
CS2
化学文摘社编号:
分子量:
76.14
UNSPSC Code:
12352107
NACRES:
NA.21
PubChem Substance ID:
EC Number:
200-843-6
Beilstein/REAXYS Number:
1098293
MDL number:
Assay:
≥99%
Grade:
anhydrous
Bp:
46 °C (lit.)
Vapor pressure:
5.83 psi ( 20 °C)
产品名称
二硫化碳, anhydrous, ≥99%
InChI key
QGJOPFRUJISHPQ-UHFFFAOYSA-N
InChI
1S/CS2/c2-1-3
SMILES string
S=C=S
grade
anhydrous
vapor density
2.67 (vs air)
vapor pressure
5.83 psi ( 20 °C)
assay
≥99%
form
liquid
autoignition temp.
212 °F
expl. lim.
50 %
impurities
<0.005% water
refractive index
n20/D 1.627 (lit.)
bp
46 °C (lit.)
mp
−112-−111 °C (lit.)
density
1.266 g/mL at 25 °C (lit.)
Quality Level
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Application
Carbon disulfide may be used in the xanthogenation of cellulose and in the synthesis of poly(ethylene trithiocarbonate) and dithiocarbamates. It can also generate 1,3-dithiolium carbenes via cycloaddition with acetylenes.
General description
Carbon disulfide is a highly volatile, flammable liquid with low ignition temperature. It is an important raw material for preparing viscose rayon and cellophane film. C2S may undergo hydrolysis catalyzed by nanosized titania and zirconia to form CO2 and H2S.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1
target_organs
Peripheral nervous system,Central nervous system,Cardio-vascular system,Eyes
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-22.0 °F - closed cup
flash_point_c
-30 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
法规信息
新产品
此项目有
1, 3-Dithiolium carbenes from acetylenes and carbon disulfide.
Hartzler HD.
Journal of the American Chemical Society, 95(13), 4379-4387 (1973)
Nanosized titania and zirconia as catalysts for hydrolysis of carbon disulfide.
Yue Y, et al.
Applied Catalysis. B, Environmental, 46(3), 561-572 (2003)
Copolymerization of ethylene sulfide and carbon disulfide.
Soga K, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 14(3), 677-684 (1976)
Carbon Disulfide.
Smith DE and Timmerman RW.
Kirk-Othmer Encyclopedia of Chemical Technology (2003)
Xanthogenation of lignocarbohydrates by carbon disulfide.
Efanov MV and Pershina LA.
Chemistry of Natural Compounds, 38(1), 90-94 (2002)
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