76735
O -（2,3,4,5,6-五氟苄基）羟胺 盐酸盐
derivatization grade (GC derivatization), LiChropur™, ≥99.0% (AT)
别名:
PFBHA·HCl
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关于此项目
线性分子式:
C6F5CH2ONH2·HCl
化学文摘社编号:
分子量:
249.57
Beilstein:
4031190
EC 号:
MDL编号:
UNSPSC代码:
23151817
PubChem化学物质编号:
NACRES:
NA.22
等级
derivatization grade (GC derivatization)
质量水平
方案
≥99.0% (AT)
表单
solid
质量
LiChropur™
反应适用性
reagent type: derivatization reagent
reaction type: Alkylations
技术
gas chromatography (GC): suitable
mp
212-218 °C
227 °C (subl.) (lit.)
溶解性
H2O: 5%, clear
SMILES字符串
Cl.NOCc1c(F)c(F)c(F)c(F)c1F
InChI
1S/C7H4F5NO.ClH/c8-3-2(1-14-13)4(9)6(11)7(12)5(3)10;/h1,13H2;1H
InChI key
HVMVKNXIMUCYJA-UHFFFAOYSA-N
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一般描述
O-（2,3,4,5,6-五氟苄基）羟胺盐酸盐（PFBHA.HCl）为衍生剂。
应用
PFBHA.HCl 用于含羰基代谢物的衍生化，随后通过 GC-MS 进行分析。也可用于醛衍生化，然后使用 GC/MS 进行醛水解。
包装
无底玻璃瓶。内含物在插入的融合锥体内。
其他说明
GC-ECD 分析羰基化合物（酮类固醇和碳水化合物）的灵敏的衍生化试剂
法律信息
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Degradation of fluoranthene by Pasteurella sp. IFA and Mycobacterium sp. PYR-1:isolation and identification of metabolites.
Sepic E, Bricelj M, Leskovsek H.
Journal of Applied Microbiology, 85(4), 746-754 null
Plasmalogen degradation by oxidative stress: production and disappearance of specific fatty aldehydes and fatty alpha-hydroxyaldehydes.
Stadelmann-Ingrand S
Free Radical Biology & Medicine, 31(10), 1263-1271 (2001)
Yun-Gon Kim et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 893-894, 177-181 (2012-03-31)
Nucleotide diphosphate (NDP) sugars are widely present in antibiotics and glycoconjugates, such as protein- and lipid-linked oligosaccharides, where they act as substrates for glycosyltransferase in eukaryotes and prokaryotes. Among NDP sugars, NDP-4-keto sugars are key intermediates in the synthesis of
Julián Zapata et al.
Analytica chimica acta, 660(1-2), 197-205 (2010-01-28)
This work presents a comparative study of the analytical characteristics of two methods for the analysis of carbonyl compounds in wine, both based on the derivatization with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA). In the first method derivatives are formed in the solid
R S Spaulding et al.
Analytical and bioanalytical chemistry, 372(7-8), 808-816 (2002-05-16)
The employment of O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine (PFBHA) derivatization along with bis-(trimethylsilyl)trifluoroacetamide (BSTFA) or N, N-( tert-butyldimethylsilyl)trifluoroacetamide (MTBSTFA) derivatization is a popular method for measurement of oxygenated organics in environmental and biological samples. Most notably, the derivatization method enables the measurement of atmospheric
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