77452
2-溴苯乙酮
purum, ≥97.0% (GC)
别名:
ω-溴苯乙酮, 苯甲酰甲基溴
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线性分子式:
C6H5COCH2Br
化学文摘社编号:
分子量:
199.04
EC Number:
200-724-9
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
606474
MDL number:
InChI key
LIGACIXOYTUXAW-UHFFFAOYSA-N
InChI
1S/C8H7BrO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2
SMILES string
BrCC(=O)c1ccccc1
grade
purum
assay
≥97.0% (GC)
bp
135 °C/18 mmHg (lit.)
mp
47-50 °C, 48-51 °C (lit.)
Gene Information
human ... PTPN6(5777)
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A Kanstrup et al.
Archives of biochemistry and biophysics, 304(2), 332-337 (1993-08-01)
A series of 18 phenacyl bromide and iodoacetamide analogues have been synthesized and used to alkylate Met-398 situated in the S'1 binding site of carboxypeptidase Y. The course of the reactions was monitored by measurements of the peptidase and esterase
Anabha E Raveendran et al.
Organic & biomolecular chemistry, 8(4), 901-905 (2010-02-06)
Nucleophilic heterocyclic carbenes (NHCs) have been used for the first time as catalysts in the cyclopropanation of ethyl cyanocinnamates with phenacyl bromide by Michael-initiated ring-closure (MIRC).
P A Wender et al.
Organic letters, 1(13), 2117-2120 (2000-06-03)
[formula: see text] 4'-Bromoacetophenone derivatives which upon excitation can generate monophenyl radicals capable of hydrogen atom abstraction were investigated as photoinducible DNA cleaving agents. Pyrrolecarboxamide-conjugated 4'-bromoacetophenones were synthesized, and their DNA cleaving activities and sequence selectivities were determined.
S Ramalingam et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(2), 826-834 (2011-01-11)
In this work, the experimental and theoretical spectra of 4-chloro-2-bromoacetophenone (4C2BAP) are studied. FT-IR and FT-Raman spectra of title molecule have been recorded in the region 4000-100 cm(-1). The structural and spectroscopic data of the molecule in the ground state
Shu-Xiang Wang et al.
Ultrasonics sonochemistry, 15(1), 33-36 (2007-09-04)
The alkylation of N-hydroxyphthalimide with alkyl halides in the presence of potassium carbonate results N-alkoxyphthalimides in 64-99% yields in DMSO under ultrasound irradiation. Compared with conventional methods, the main advantages of the present procedure are milder conditions, shorter reaction time
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