80430
二氯二甲基硅烷
Wacker Chemie AG, ≥99.0% (GC)
别名:
硅烷 M2, DMDCS, 二甲基二氯硅烷
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线性分子式:
(CH3)2SiCl2
化学文摘社编号:
分子量:
129.06
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-901-0
Beilstein/REAXYS Number:
605287
MDL number:
Assay:
≥99.0% (GC)
Form:
liquid
InChI key
LIKFHECYJZWXFJ-UHFFFAOYSA-N
InChI
1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3
SMILES string
C[Si](C)(Cl)Cl
assay
≥99.0% (GC)
form
liquid
manufacturer/tradename
Wacker Chemie AG
Quality Level
bp
70 °C (lit.)
mp
−76 °C (lit.)
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General description
Dichlorodimethylsilane is an organosilicon compound generally used as a protecting group for diols and carbonyl compounds. It is also used as a starting material for the preparation of silicon-based reagents.
Application
Dichlorodimethylsilane can be used:
- As a silane coupling agent in the synthesis of silica nanoparticles and in their surface modification studies.
- To prepare polydimethylsiloxane microemulsions by reacting with sodium dodecylpolyoxyethylene sulfate.
- To prepare a novel heterasumanene where the benzylic carbon atoms of the sumanene are replaced by heteroatom (S, Si) functionalities
Other Notes
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
flash_point_f
33.8 °F - closed cup
flash_point_c
1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Zhongyan Lu et al.
American journal of physiology. Regulatory, integrative and comparative physiology, 307(5), R558-R570 (2014-06-13)
Ruminal fermentation products such as short-chain fatty acids (SCFA) and CO2 acutely stimulate urea transport across the ruminal epithelium in vivo, whereas ammonia has inhibitory effects. Uptake and signaling pathways remain obscure. The ruminal expression of SLC14a1 (UT-B) was studied
Wonmi Ahn et al.
ACS nano, 4(7), 4181-4189 (2010-06-23)
Uniform hexagonal arrays of diverse nanotemplated metal structures were formed via selective electroless gold plating on particle-lithographed dimethyldichlorosilane layers. Surface-associated water at silica bead interstices was shown to correlate with the formation of silane rings with outer ring diameters ranging
R Bos et al.
Microbiology (Reading, England), 142 ( Pt 9), 2355-2361 (1996-09-01)
Co-adhesion between oral microbial pairs (i.e. adhesion of a planktonic microorganism to a sessile organism adhering to a substratum surface) has been described as a highly specific interaction, mediated by stereochemical groups on the interacting microbial cell surfaces, and also
Zhan-Hui Wang et al.
Journal of immunological methods, 285(2), 237-243 (2004-02-26)
In the development of biosensors, the immobilization of biomolecules at interfaces played a crucial role. The feasibility of using 3-aminopropyltriethoxysilane (APTES) and glutaraldehyde (Glu) to modify silicon surface to immobilize covalently protein for immunoassay with the biosensor based on imaging
Takehiro Fukuzaki et al.
Organic letters, 4(17), 2877-2880 (2002-08-17)
[reaction: see text] Studies on the connection between the right and left segments of azadirachtin are described. The Ireland-Claisen rearrangement of Li-enolate of the modeled ester with dichlorodimethylsilane in toluene afforded the desired limonoid framework stereoselectively in good yield.
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