87472
Hydrogen chloride solution
~3 M in 1-butanol, derivatization grade (GC derivatization), LiChropur™
产品名称
氯化氢 - 1-丁醇 溶液, ~3 M in 1-butanol, derivatization grade (GC derivatization), LiChropur™
等级
derivatization grade (GC derivatization)
质量水平
表单
solution
质量
LiChropur™
反应适用性
reagent type: derivatization reagent
reaction type: Acylations
浓度
~3 M in 1-butanol
技术
gas chromatography (GC): suitable
密度
0.87 g/mL at 20 °C
储存温度
2-8°C
SMILES字符串
Cl
InChI
1S/ClH/h1H
InChI key
VEXZGXHMUGYJMC-UHFFFAOYSA-N
一般描述
Acylation, an alternative to silylation, is the conversion of compounds that contain active hydrogens (-OH, -SH and -NH) into esters, thioesters, and amides through the action of a carboxylic acid or derivative. The presence of a carbonyl group adjacent to the halogenated carbons enhances electron capture detector (ECD) response. Acylation has many benefits:
Hydrogen chloride-1-butanol is a reagent utilized to form fragmentation-directing derivatives for GC/MS analysis.
- It improves the stability of compounds by protecting unstable groups.
- It may confer volatility on substances such as carbohydrates or amino acids, which have so many polar groups that they are non-volatile and normally decompose on heating.
- It assists in separations not possible with underivatized compounds.
- Compounds are detectable at very low levels with an ECD.
Hydrogen chloride-1-butanol is a reagent utilized to form fragmentation-directing derivatives for GC/MS analysis.
应用
Hydrogen chloride - 1-butanol solution has been used for butylation of amino acids during blood sample analysis for determination of ethylenediaminetetraacetic acid using mass spectrometry.
其他说明
Reagent for the esterification of amino acids and carnites for GC-MS analysis.
法律信息
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
易制毒化学品（3类）
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商品
In this article we provide a complete workflow of quantification and identification of acylcarnitines in dried blood spots (DBS) using stable isotope-labeled (SIL) acylcarnitines CRMs by FIA-MS/MS.
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