87472
Hydrogen chloride solution
~3 M in 1-butanol, derivatization grade (GC derivatization), LiChropur™
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关于此项目
化学文摘社编号:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352301
MDL number:
Beilstein/REAXYS Number:
1098214
Concentration:
~3 M in 1-butanol
Form:
solution
Grade:
derivatization grade (GC derivatization)
产品名称
氯化氢 - 1-丁醇 溶液, ~3 M in 1-butanol, derivatization grade (GC derivatization), LiChropur™
grade
derivatization grade (GC derivatization)
Quality Level
form
solution
quality
LiChropur™
reaction suitability
reagent type: derivatization reagent
reaction type: Acylations
concentration
~3 M in 1-butanol
technique(s)
gas chromatography (GC): suitable
density
0.87 g/mL at 20 °C
storage temp.
2-8°C
SMILES string
Cl
InChI
1S/ClH/h1H
InChI key
VEXZGXHMUGYJMC-UHFFFAOYSA-N
General description
Acylation, an alternative to silylation, is the conversion of compounds that contain active hydrogens (-OH, -SH and -NH) into esters, thioesters, and amides through the action of a carboxylic acid or derivative. The presence of a carbonyl group adjacent to the halogenated carbons enhances electron capture detector (ECD) response. Acylation has many benefits:
Hydrogen chloride-1-butanol is a reagent utilized to form fragmentation-directing derivatives for GC/MS analysis.
- It improves the stability of compounds by protecting unstable groups.
- It may confer volatility on substances such as carbohydrates or amino acids, which have so many polar groups that they are non-volatile and normally decompose on heating.
- It assists in separations not possible with underivatized compounds.
- Compounds are detectable at very low levels with an ECD.
Hydrogen chloride-1-butanol is a reagent utilized to form fragmentation-directing derivatives for GC/MS analysis.
Application
Hydrogen chloride - 1-butanol solution has been used for butylation of amino acids during blood sample analysis for determination of ethylenediaminetetraacetic acid using mass spectrometry.
Other Notes
Reagent for the esterification of amino acids and carnites for GC-MS analysis.
Legal Information
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
易制毒化学品（3类）
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In this article we provide a complete workflow of quantification and identification of acylcarnitines in dried blood spots (DBS) using stable isotope-labeled (SIL) acylcarnitines CRMs by FIA-MS/MS.
M S Rashed et al.
Clinical chemistry, 43(7), 1129-1141 (1997-07-01)
Metabolic profiling of amino acids and acylcarnitines from blood spots by automated electrospray tandem mass spectrometry (ESI-MS/MS) is a powerful diagnostic tool for inborn errors of metabolism. New approaches to sample preparation and data interpretation have helped establish the methodology
Q Miao et al.
Physical review letters, 109(23), 233905-233905 (2013-02-02)
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Woo Seok Yang et al.
Journal of ethnopharmacology, 146(2), 637-644 (2013-02-16)
Archidendron clypearia Jack. (Fabaceae) is a representative ethnomedicinal herbal plant prescribed for various inflammatory diseases such as pharyngolaryngitis and tonsillitis. However, the pharmacology behind this plant's anti-inflammatory properties has not been fully understood. Therefore, in this study, the anti-inflammatory mechanism
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 87472-250ML-F | 04061833052730 |
| 87472-50ML-F | 04061833052747 |