87751
二酰胺
≥99.0% (CHN)
别名:
1,1′-偶氮二（N，N二甲基甲酰胺）, N,N,N′,N′-四甲基偶氮二甲酰胺, TMAD, 二氮杂二羧酸双（N，N-二甲基酰胺）, 偶氮二羧酸双（二甲基酰胺）
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线性分子式:
(CH3)2NCON=NCON(CH3)2
化学文摘社编号:
分子量:
172.19
EC Number:
233-951-7
UNSPSC Code:
12352202
PubChem Substance ID:
Beilstein/REAXYS Number:
1910409
MDL number:
assay
≥99.0% (CHN)
form
crystalline
color
yellow
storage temp.
−20°C
SMILES string
CN(C)C(=O)\N=N\C(=O)N(C)C
InChI
1S/C6H12N4O2/c1-9(2)5(11)7-8-6(12)10(3)4/h1-4H3/b8-7+
InChI key
VLSDXINSOMDCBK-BQYQJAHWSA-N
Other Notes
Reagent for Mitsunobu reactions of acids with high pK′s ; synthesis of cyclic ethers from diols
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
S. Harusawa et al.
Tetrahedron Letters, 37, 2463 -2463 (1996)
T. Tsunoda et al.
Chemistry Letters (Jpn), 539-539 (1994)
Mykhaylo A Potopnyk et al.
Organic letters, 14(16), 4258-4261 (2012-08-03)
A convenient route to macrocyclic diamide-linked macrocyclic derivatives with a sucrose scaffold is presented. Reaction of sucrose based amines (o- and m-) with acid dichlorides afforded the monomeric macrocycles in excellent yields, while reaction of the p-amines also provided dimeric