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Merck
CN

88965

Supelco

环丁砜

analytical standard

别名:

四亚甲基砜, 四氢噻吩-1,1-二氧化物

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关于此项目

经验公式(希尔记法):
C4H8O2S
CAS Number:
分子量:
120.17
Beilstein:
107765
EC 号:
MDL编号:
UNSPSC代码:
41116107
PubChem化学物质编号:
NACRES:
NA.24
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等级

analytical standard

质量水平

蒸汽密度

4.2 (vs air)

蒸汽压

0.01 mmHg ( 20 °C)

方案

≥99.8% (GC)

保质期

limited shelf life, expiry date on the label

技术

HPLC: suitable
gas chromatography (GC): suitable

折射率

n20/D 1.484 (lit.)
n20/D 1.485

沸点

104 °C/0.2 mmHg (lit.)
285 °C (lit.)

mp

20-26 °C (lit.)

密度

1.261 g/mL at 25 °C (lit.)

应用

environmental

包装形式

neat

SMILES字符串

O=S1(=O)CCCC1

InChI

1S/C4H8O2S/c5-7(6)3-1-2-4-7/h1-4H2

InChI key

HXJUTPCZVOIRIF-UHFFFAOYSA-N

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相关类别

一般描述

Sulfolane is an aprotic polar solvent, used in the separation of aromatic hydrocarbons from aliphatic hydrocarbons.
Sulfolane is widely used in combination with diisopropanolamine in the sulfinol process of removal of toxic levels of hydrogen sulfide and carbonyl sulfide from raw natural gas condensate. It is also used as an industrial solvent for photographic chemicals, polymer, and petrochemical industries.

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Sulfolane may be used as an analytical reference standard for the quantification of the analyte in groundwater samples using gas chromatography-mass spectrometry technique.

象形图

Health hazardExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Repr. 1B

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

闪点(°F)

350.6 °F - closed cup

闪点(°C)

177 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Thermochemical conversion of cellulose in polar solvent (sulfolane) into levoglucosan and other low molecular-weight substances
Kawamoto.H, et al.
Journal of Analytical and Applied Pyrolysis, 70, 303-313 (2003)
Industrial Solvents Handbook, Revised And Expanded (2003)
Kevin Aart Douglass et al.
Journal of the American Society for Mass Spectrometry, 23(3), 489-497 (2012-01-06)
The supercharging effect of sulfolane on cytochrome c (cyt c) during electrospray ionization mass spectrometry (ESI-MS) in the absence of conformational effects was investigated. The addition of sulfolane on the order of 1 mM or greater to denaturing solutions of cyt
François Versace et al.
Analytical and bioanalytical chemistry, 404(6-7), 1831-1838 (2012-08-25)
The role of busulfan (Bu) metabolites in the adverse events seen during hematopoietic stem cell transplantation and in drug interactions is not explored. Lack of availability of established analytical methods limits our understanding in this area. The present work describes
Haruo Kawamoto et al.
Carbohydrate research, 343(2), 249-255 (2007-11-30)
Boric acid inhibited the acid-catalyzed depolymerization of cellulose in sulfolane, a non-aqueous medium, at high temperature. Formation of the dehydration products such as levoglucosenone, furfural, and 5-hydroxymethyl furfural were also effectively inhibited. Similar inhibition was observed for cellooligosaccharides and starch

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