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Merck
CN

B11400

苯并三唑

99%, powder, ReagentPlus®

别名:

1,2,3-苯并三氮唑, 1H-苯并三氮唑

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关于此项目

经验公式(希尔记法):
C6H5N3
化学文摘社编号:
分子量:
119.12
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
202-394-1
MDL number:
Beilstein/REAXYS Number:
112133
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产品名称

苯并三唑, ReagentPlus®, 99%

InChI key

QRUDEWIWKLJBPS-UHFFFAOYSA-N

InChI

1S/C6H5N3/c1-2-4-6-5(3-1)7-9-8-6/h1-4H,(H,7,8,9)

SMILES string

c1ccc2[nH]nnc2c1

vapor density

4.1 (vs air)

vapor pressure

0.04 mmHg ( 20 °C)

product line

ReagentPlus®

assay

99%

form

powder

mp

97-99 °C (lit.)

Quality Level

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Application

苯并三唑可用作反应物以合成:
  • 以对甲苯磺酸作为催化剂通过仲胺和醛的曼尼希反应合成β-氨基羰基化合物
  • 通过与硝基苯甲酸的亚硫酰氯催化反应合成酰基苯并三唑
  • 以甲苯作为溶剂通过与 2-溴吡啶发生反应合成1-(2-吡啶基)苯并三唑

General description

苯并三唑可用作合成辅助剂,用于制备有机衍生物,也是铜及其合金的缓蚀剂。

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Exclamation markEnvironment

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

338.0 °F - closed cup

flash_point_c

170 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Derivatization of 1-phenyl substituted 4-amino-2-benzazepin-3-ones: evaluation of Pd-catalyzed coupling reactions
Ballet S, et al.
Tetrahedron, 63, 3718-3727 (2007)
Synthesis, Characterization and Energetic Properties of 1, 3, 4-Oxadiazoles
Wang Z, et al.
European Journal of Organic Chemistry, 2015, 5183-5188 (2015)
Martin Krug et al.
ChemMedChem, 6(1), 63-72 (2010-12-09)
Within the last decade, interest in the development of new anticancer drugs increased mainly from emerging resistance against established drugs, which were found to be limited by the multidrug resistance (MDR) phenomenon. Several anticancer targets have been investigated for the
Inhibition of copper corrosion by 1, 2, 3-benzotriazole: a review
Matjavz F et al.
Corrosion Science, 52, 2737-2749 (2010)
Benzotriazole as a synthetic auxiliary: benzotriazolylalkylations and benzotriazole-mediated heteroalkylation
Alan K R et al.
Synthesis, 1994, 445-456 (1994)

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