L3900
2,6-二甲基吡啶
ReagentPlus®, 98%
别名:
2,6-卢剔啶
质量水平
产品线
ReagentPlus®
方案
98%
表单
liquid
折射率
n20/D 1.497 (lit.)
沸点
143-145 °C ((lit.))
143-145 °C (lit.)
mp
-6 °C
−6 °C (lit.)
密度
0.92 g/mL at 25 °C ((lit.))
0.92 g/mL at 25 °C (lit.)
SMILES字符串
CCCCCCCCCCCC(=O)ON1C(=O)CCC1=O
Cc1cccc(C)n1
InChI
1S/C16H27NO4/c1-2-3-4-5-6-7-8-9-10-11-16(20)21-17-14(18)12-13-15(17)19/h2-13H2,1H3
1S/C7H9N/c1-6-4-3-5-7(2)8-6/h3-5H,1-2H3
InChI key
LRKGVVJOUNKTGG-UHFFFAOYSA-N
OISVCGZHLKNMSJ-UHFFFAOYSA-N
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应用
2,6-二甲基吡啶可用作碱，在 4-乙酰氨基-2,2,6,6-四甲基哌啶-1-氧代铵四氟硼酸盐（Bobbitt 盐）存在下将 α-CF3 醇氧化成相应的羰基化合物
可用于：
可用于：
- 作为在手性 Pd（II）-双膦配合物存在下催化不对称氟化 α-氰基膦酸盐的促进剂。
- 与叔丁基二甲基甲硅烷基三氟甲磺酸酯组合，用于保护叔醇和非反应性仲醇。
- 与三乙基甲硅烷基三氟甲磺酸盐组合，用于在二氯甲烷中将缩醛转化为相应的醛，然后在水中进行检测。
法律信息
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
91.4 °F
闪点(°C)
33 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Pd (II)-Catalyzed Asymmetric Fluorination of ?-Aryl-?-cyanophosphonates with the Aid of 2, 6-Lutidine.
Moriya K I, et al.
Synlett, 2007(07), 1139-1142 (2007)
Studies with trialkylsilyltriflates: new syntheses and applications.
Corey E J, et al.
Tetrahedron Letters, 22(36), 3455-3458 (1981)
Unexpected Highly Chemoselective Deprotection of the Acetals from Aldehydes and Not Ketones: TESOTf? 2, 6-Lutidine Combination.
Fujioka H, et al.
Journal of the American Chemical Society, 126(38), 11800-11801 (2004)
Synthesis of 4-acetamido-2, 2, 6, 6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate and 4-acetamido-(2, 2, 6, 6-tetramethyl-piperidin-1-yl) oxyl and their use in oxidative reactions.
Mercadante M A, et al.
Nature Protocols, 8(4), 666-666 (2013)
Elisabetta Fanizza et al.
International journal of molecular sciences, 20(13) (2019-06-30)
The low photostability of conventional organic dyes and the toxicity of cadmium-based luminescent quantum dots have prompted the development of novel probes for in vitro and in vivo labelling. Here, a new fluorescent lanthanide probe based on silica nanoparticles is
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