130206
硝基乙烷
reagent grade, ≥98.0%
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关于此项目
线性分子式:
CH3CH2NO2
化学文摘社编号:
分子量:
75.07
PubChem Substance ID:
UNSPSC Code:
12352102
Beilstein/REAXYS Number:
1209324
MDL number:
Assay:
≥98.0%
Grade:
reagent grade
Bp:
114-115 °C (lit.)
Vapor pressure:
15.6 mmHg ( 20 °C)
refractive index
n20/D 1.391 (lit.)
bp
114-115 °C (lit.)
mp
−90 °C (lit.)
solubility
acetone: soluble(lit.), alcohol: soluble(lit.), water: slightly soluble(lit.)
density
1.045 g/mL at 25 °C (lit.)
SMILES string
CC[N+]([O-])=O
InChI
1S/C2H5NO2/c1-2-3(4)5/h2H2,1H3
InChI key
MCSAJNNLRCFZED-UHFFFAOYSA-N
grade
reagent grade
vapor density
2.58 (vs air)
vapor pressure
15.6 mmHg ( 20 °C)
assay
≥98.0%
form
liquid
autoignition temp.
778 °F
expl. lim.
3.4 %
Quality Level
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General description
Nitroethane reacts with sodium to afford sodium-nitroethane. Solution of nitroethane in caustic potash reacts with bromine to afford monobromnitroethane. It can undergo nitroaldol (Henry) condensation reaction with various aldehydes in the presence of copper(II) arylhydrazone complexes (catalyst).
pK of nitroethane is 8.60.4
Nitroethane is an aprotic solvent with high polarity, which on oxidation with glucose oxidase gives nitrite, acetaldehyde and hydrogen peroxide as the major products.
pK of nitroethane is 8.60.4
Nitroethane is an aprotic solvent with high polarity, which on oxidation with glucose oxidase gives nitrite, acetaldehyde and hydrogen peroxide as the major products.
Application
Nitroethane may be used in the synthesis of the following compounds:
- β-nitro amine derivatives
- β-aryl nitroethylenes
- 2-alkylthio-3-alkylamino-1-aryl(hetaryl)-4-nitropentene
Other Notes
主要杂质为 2-硝基丙烷
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 3 - Muta. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
87.8 °F - closed cup
flash_point_c
31 °C - closed cup
法规信息
新产品
此项目有
Limin Xiang et al.
Nature communications, 9(1), 1435-1435 (2018-04-14)
Under ambient conditions, the behavior of a solid surface is often dominated by a molecularly thin adsorbed layer (adlayer) of small molecules. Here we develop an optical approach to unveil the nanoscale structure and composition of small-molecule adlayers on glass
Mechanism of oxidation of nitroethane by glucose oxidase
Porters.T.JD and Bright.JH
The Journal of Biological Chemistry, 252, 4361- 4370 (1977)
Volumetric and Viscometric Properties of Binary Mixtures of Aliphatic Alcohols (C1- C4) with Nitroethane from 293.15 K to 313.15 K
Tu H-C, et al.
Journal of Chemical and Engineering Data, 45(3), 450-456 (2000)
Copper (II) arylhydrazone complexes as catalysts for C-H activation in the Henry reaction in water
Ma Z, et al.
J. Mol. Catal. A: Chem. (2016)
Feng-Wu Liu et al.
Carbohydrate research, 344(18), 2439-2443 (2009-11-03)
Henry reactions of a novel higher sugar derivative, (1R)-(1,4:3,6-dianhydro-D-mannitol-2-yl)-1,4:3,6-dianhydro-D-fructose 5,5'-dinitrate (Alternate nomenclature: (1R)-(isomannid-2-yl)-1,4:3,6-dianhydro-D-fructose 5,5'-dinitrate), with nitromethane and nitroethane were studied. The kinetic and thermodynamic reactions with nitromethane under different conditions were carried out to afford (2S)- and (2R)-beta-nitroalcohols, respectively. But
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