等级
reagent grade
质量水平
蒸汽密度
2.58 (vs air)
蒸汽压
15.6 mmHg ( 20 °C)
方案
≥98.0%
表单
liquid
自燃温度
778 °F
expl. lim.
3.4 %
折射率
n20/D 1.391 (lit.)
沸点
114-115 °C (lit.)
mp
−90 °C (lit.)
溶解性
acetone: soluble(lit.)
alcohol: soluble(lit.)
water: slightly soluble(lit.)
密度
1.045 g/mL at 25 °C (lit.)
SMILES字符串
CC[N+]([O-])=O
InChI
1S/C2H5NO2/c1-2-3(4)5/h2H2,1H3
InChI key
MCSAJNNLRCFZED-UHFFFAOYSA-N
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一般描述
Nitroethane reacts with sodium to afford sodium-nitroethane. Solution of nitroethane in caustic potash reacts with bromine to afford monobromnitroethane. It can undergo nitroaldol (Henry) condensation reaction with various aldehydes in the presence of copper(II) arylhydrazone complexes (catalyst).
pK of nitroethane is 8.60.4
Nitroethane is an aprotic solvent with high polarity, which on oxidation with glucose oxidase gives nitrite, acetaldehyde and hydrogen peroxide as the major products.
pK of nitroethane is 8.60.4
Nitroethane is an aprotic solvent with high polarity, which on oxidation with glucose oxidase gives nitrite, acetaldehyde and hydrogen peroxide as the major products.
应用
Nitroethane may be used in the synthesis of the following compounds:
- β-nitro amine derivatives
- β-aryl nitroethylenes
- 2-alkylthio-3-alkylamino-1-aryl(hetaryl)-4-nitropentene
其他说明
主要杂质为 2-硝基丙烷
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 3 - Muta. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
87.8 °F - closed cup
闪点(°C)
31 °C - closed cup
法规信息
新产品
Limin Xiang et al.
Nature communications, 9(1), 1435-1435 (2018-04-14)
Under ambient conditions, the behavior of a solid surface is often dominated by a molecularly thin adsorbed layer (adlayer) of small molecules. Here we develop an optical approach to unveil the nanoscale structure and composition of small-molecule adlayers on glass
Volumetric and Viscometric Properties of Binary Mixtures of Aliphatic Alcohols (C1- C4) with Nitroethane from 293.15 K to 313.15 K
Tu H-C, et al.
Journal of Chemical and Engineering Data, 45(3), 450-456 (2000)
Copper (II) arylhydrazone complexes as catalysts for C-H activation in the Henry reaction in water
Ma Z, et al.
J. Mol. Catal. A: Chem. (2016)
Annie Héroux et al.
Biochemistry, 48(15), 3407-3416 (2009-03-07)
The flavoenzyme nitroalkane oxidase is a member of the acyl-CoA dehydrogenase superfamily. Nitroalkane oxidase catalyzes the oxidation of neutral nitroalkanes to nitrite and the corresponding aldehydes or ketones. Crystal structures to 2.2 A resolution or better of enzyme complexes with
Matheus P Freitas et al.
The journal of physical chemistry. A, 111(30), 7233-7236 (2007-07-10)
The stabilities of the gauche and anti conformations of butane, 1,2-dicyanoethane (DCE), and 1,2-dinitroethane (DNE) have been investigated through theoretical calculations. The gauche effect-the tendency of keeping close vicinal electronegative substituents (thetaX-C-C-X approximately 60 degrees ) in an ethane fragment-is
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