等级
technical grade
方案
≥95%
表单
solid
mp
194 °C (lit.)
SMILES字符串
[Cs+].CC([O-])=O
InChI
1S/C2H4O2.Cs/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
InChI key
ZOAIGCHJWKDIPJ-UHFFFAOYSA-M
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一般描述
Cesium acetate is an inorganic salt. It has been reported to change the surface of kaolinite by undergoing intercalation under various reaction conditions. It modifies the catalytic activity of MCM (Mobil Composition of Matter) -41 and MCM-48-type mesoporous molecular sieves by undergoing ion exchange with cesium cations and impregnation on their surfaces.
应用
Cesium acetate may be used for the inversion of secondary alcohols to afford inverted acetates. It can also be used for the inversion of cyclopentyl and cyclohexyl alcohols.
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
A procedure for alcohol inversion using cesium acetate.
Huffman JW and Desai RC.
Synthetic Communications, 13(7), 553-557 (1983)
Cesium-modified mesoporous molecular sieves as basic catalysts for Knoevenagel condensations.
Ernst S, et al.
Studies in Surface Science and Catalysis, 125, 367-374 (1999)
Efficient inversions of secondary alcohols using cesium acetate and 18-crown-6.
Torisawa Y, et al.
Chemistry Letters (Jpn), 9, 1555-1556 (1984)
Modification of kaolinite surfaces with cesium acetate at 25, 120, and 220 C.
Frost RL, et al.
Langmuir, 15(26), 8787-8794 (1999)
Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate.
Shimizu T, et al.
Tetrahedron Letters, 37(34), 6145-6148 (1996)
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