212946
氯化亚铜
reagent grade, 97%
别名:
一氯化铜
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关于此项目
线性分子式:
CuCl
化学文摘社编号:
分子量:
99.00
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-842-9
MDL number:
Assay:
97%
Grade:
reagent grade
Form:
powder
Solubility:
dimethyl sulfide: partially soluble(lit.), water: insoluble(lit.)
grade
reagent grade
Quality Level
vapor pressure
1.3 mmHg ( 546 °C)
assay
97%
form
powder
reaction suitability
reagent type: catalyst
core: copper
pH
5 (20 °C, 50 g/L)
bp
1490 °C (lit.)
mp
430 °C (lit.)
solubility
dimethyl sulfide: partially soluble(lit.), water: insoluble(lit.)
SMILES string
Cl[Cu]
InChI
1S/ClH.Cu/h1H;/q;+1/p-1
InChI key
OXBLHERUFWYNTN-UHFFFAOYSA-M
General description
Cu 在 CuCl 中以 + 1（亚铜）价态存在。CuCl 是一种具有宽带隙的半导体。由于其晶格与硅相似，因此是硅光电器件的一种很有前途的候选材料。参与格氏试剂的各种反应。
Application
氯化铜 (I)（氯化亚铜，CuCl）已用于合成 7-（（叔 -丁基二甲基硅基）氧）七-2,4-二炔-1-醇。CuCl 可用于环共轭二烯的立体定向合成。它可用作研究氯化铜络合物在水热溶液中稳定性的反应物。
作为自由基反应（如 α,β-不饱和酮的锡氢化作用）的引发剂表现出独特的性质。
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signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Copper (I) chloride-mediated intramolecular coupling of vinyltrimethylstannane and vinyl halide functions.
Piers E and Wong T.
The Journal of Organic Chemistry, 58(14), 3609-3610 (1993)
Xiaoliang Xu et al.
Organic letters, 12(5), 897-899 (2010-02-04)
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| F4537-50UG | 04061833617793 |
| 212946-500G | 04061835276608 |
| 212946-25G | 04061838772503 |
| 212946-2KG | 04061838772510 |