212946
氯化亚铜
reagent grade, 97%
别名:
一氯化铜
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关于此项目
线性分子式:
CuCl
化学文摘社编号:
分子量:
99.00
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-842-9
MDL number:
Assay:
97%
Grade:
reagent grade
Form:
powder
Solubility:
dimethyl sulfide: partially soluble(lit.)
water: insoluble(lit.)
water: insoluble(lit.)
产品名称
氯化亚铜, reagent grade, 97%
InChI key
OXBLHERUFWYNTN-UHFFFAOYSA-M
InChI
1S/ClH.Cu/h1H;/q;+1/p-1
SMILES string
Cl[Cu]
grade
reagent grade
vapor pressure
1.3 mmHg ( 546 °C)
assay
97%
form
powder
reaction suitability
reagent type: catalyst
core: copper
pH
5 (20 °C, 50 g/L)
bp
1490 °C (lit.)
mp
430 °C (lit.)
solubility
dimethyl sulfide: partially soluble(lit.)
water: insoluble(lit.)
Quality Level
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Application
作为自由基反应（如 α,β-不饱和酮的锡氢化作用）的引发剂表现出独特的性质。
氯化铜 (I)（氯化亚铜，CuCl）已用于合成 7-（（叔 -丁基二甲基硅基）氧）七-2,4-二炔-1-醇。CuCl 可用于环共轭二烯的立体定向合成。它可用作研究氯化铜络合物在水热溶液中稳定性的反应物。
General description
Cu 在 CuCl 中以 + 1（亚铜）价态存在。CuCl 是一种具有宽带隙的半导体。由于其晶格与硅相似，因此是硅光电器件的一种很有前途的候选材料。参与格氏试剂的各种反应。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Copper (I) chloride-mediated intramolecular coupling of vinyltrimethylstannane and vinyl halide functions.
Piers E and Wong T.
The Journal of Organic Chemistry, 58(14), 3609-3610 (1993)
Experimental study of copper (I) chloride complexing in hydrothermal solutions at 40 to 300 ?C and saturated water vapor pressure.
Xiao Z, et al.
Geochimica et Cosmochimica Acta, 62(17), 2949-2964 (1998)
Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Xiaoliang Xu et al.
Organic letters, 12(5), 897-899 (2010-02-04)
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.
Yin-Hua Shih et al.
Head & neck, 35(2), 250-256 (2012-03-01)
Lysyl oxidase (LOX) is a copper-dependent enzyme that cross-links collagen and elastin in the extracellular matrix. LOX overexpressed in various tumors. The manner in which LOX affects tumor growth remains controversial. Chemical treatment and gene transfection were used to induce
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