249882
三氯化铝 溶液
1.0 M in nitrobenzene
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关于此项目
经验公式（希尔记法）:
AlCl3
化学文摘社编号:
分子量:
133.34
NACRES:
NA.55
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
liquid
产品名称
三氯化铝 溶液, 1.0 M in nitrobenzene
InChI
1S/Al.3ClH/h;3*1H/q+3;;;/p-3
SMILES string
Cl[Al](Cl)Cl
InChI key
VSCWAEJMTAWNJL-UHFFFAOYSA-K
form
liquid
reaction suitability
reagent type: catalyst
core: aluminum
concentration
0.95-1.10 M (EDTA titration)
1.0 M in nitrobenzene
density
1.249 g/mL at 25 °C
Quality Level
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signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - STOT RE 1 Inhalation
target_organs
Blood
supp_hazards
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
190.4 °F - closed cup
flash_point_c
88 °C - closed cup
法规信息
危险化学品
此项目有
Acceleration of the Diels-Alder reaction by aluminum chloride.
Yates P and Eaton P.
Journal of the American Chemical Society, 82(16), 4426-4437 (1960)
Zhiliang Huang et al.
Organic & biomolecular chemistry, 11(11), 1810-1814 (2013-02-08)
AlCl(3) promoted Friedel-Crafts acylation between 4-tert-butylbenzoyl chloride and mesitylene was investigated. The donor-acceptor complex was observed as the major species. Kinetic investigation demonstrated that the reaction was first-order on the donor-acceptor complex and zero-order on ArH, suggesting that the donor-acceptor
Amination of< i> exo</i>-2-chloronorbornane and norbornane with trichloramine-aluminum chloride.
Kovacic P, et al.
Tetrahedron, 26(2), 529-538 (1970)
Bagineni Prasad et al.
Chemical communications (Cambridge, England), 48(84), 10434-10436 (2012-09-20)
A conceptually new and straightforward introduction of sulfonyl groups at the C-7 position of an indole ring has been achieved via AlCl(3) mediated unexpected regioselective sulfonyl group migration for N-alkyl/aryl/heteroarylsulfonyl indoles affording potential inhibitors of Mycobacterium tuberculosis H37Rv chorismate mutase.
Diagnosis and management of hyperhidrosis.
R A Benson et al.
BMJ (Clinical research ed.), 347, f6800-f6800 (2013-11-28)
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