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A3407

6-(4-叠氮-2-硝基苯胺基)己酸 N-羟基琥珀酰亚胺酯

Name: 6-(4-叠氮-2-硝基苯胺基)己酸 N-羟基琥珀酰亚胺酯
Brand: SIGMA

≥85%, powder

别名:

N-琥珀酰亚胺基-6-(4-叠氮-2-硝基苯胺基)己酸酯

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关于此项目

经验公式（希尔记法）:

C₁₆H₁₈N₆O₆

化学文摘社编号:

64309-05-3

分子量:

390.35

UNSPSC Code:

12352200

PubChem Substance ID:

24890767

MDL number:

MFCD00049058

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属性

assay

≥85%

form

powder

color

orange

solubility

ethyl acetate: 10 mg/mL, DMF: soluble

storage temp.

−20°C

SMILES string

[O-][N+](=O)c1cc(ccc1NCCCCCC(=O)ON2C(=O)CCC2=O)N=[N+]=[N-]

说明

Application

具有延长间隔的光敏、双异官能化交联剂。通常情况下，初始反应通过在 6.5 至 8.5 的 pH 范围内形成酰胺键将酯连接至伯胺。紫外光 (250-350nm) 照射的过程中通过激活氮宾发生二次键合。后一次键合快速并且具有非特异性。

Other Notes

需要注意的是，相比简单的芳基叠氮化合物，硝基取代基提供的吸收谱带波长更长。

Disclaimer

还原剂（如硫醇）可将叠氮化合物还原为胺，因此应当避免还原剂出现在反应中。初始操作和偶联应当在弱光照条件下进行。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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J B Monahan et al.

The Journal of biological chemistry, 258(8), 5056-5062 (1983-04-25)

The association of the eighth (C8) and ninth (C9) components of human complement within membrane-bound C5b-9 was investigated using the photosensitive cross-linking reagent N-succinimidyl-6-(4'-azido-2'-nitrophenylamino)hexanoate. Reaction of this reagent with either the purified alpha-gamma or beta subunit of C8 resulted in

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G A Marguerie et al.

European journal of biochemistry, 139(1), 5-11 (1984-02-15)

Fibrinogen participates in platelet aggregation via specific inducible receptors on the cell surface. We have used a photoactivable bifunctional reagent, N-succinimidyl-6-(4'-azido-2'-nitrophenylamino)hexanoate, SANAH, to derivatize 125I-labeled-fibrinogen (125I-Fg) and crosslink it to ADP-stimulated platelets. Binding experiments established that 125I-Fg and 125I-Fg-SANAH interacted

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