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Merck
CN

F0378

氯甲酸-9-芴基甲酯

别名:

9-芴甲氧羰酰氯, Fmoc-Cl, 芴甲氧羰酰氯

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关于此项目

经验公式(希尔记法):
C15H11ClO2
化学文摘社编号:
分子量:
258.70
EC Number:
249-313-6
UNSPSC Code:
12352200
MDL number:
Beilstein/REAXYS Number:
2279177
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mp

62-64 °C (lit.)

storage temp.

2-8°C

SMILES string

ClC(=O)OCC1c2ccccc2-c3ccccc13

InChI

1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2

InChI key

IRXSLJNXXZKURP-UHFFFAOYSA-N

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Application

在氨基酸 HPLC 分析中,用于衍生化氨基酸;在固相肽合成中用于制备 N-Fmoc 氨基酸。

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Guoying Cao et al.
The Journal of antimicrobial chemotherapy, 62(5), 1009-1014 (2008-09-04)
The purpose of this study was to develop a specific, sensitive, accurate and reproducible high-performance liquid chromatographic (HPLC) method to measure polymyxin B in human plasma. Derivatization of polymyxin B with fluorescent 9-fluorenylmethyl chloroformate (FMOC-Cl) was performed in the same
Mei-Fen Xie et al.
Journal of separation science, 34(3), 241-246 (2011-01-27)
In this study, we investigated a simple, sensitive and reliable liquid chromatography-fluorescence detection method for the determination of memantine hydrochloride in rat plasma which was based on derivatization with 9-fluorenylmethyl chloroformate (FMOC-Cl). For the first time, FMOC-Cl was introduced into
Kun Qian et al.
Analytica chimica acta, 635(2), 222-226 (2009-02-17)
A pre-column derivatization high-performance liquid chromatographic method for glyphosate analysis has been developed. Derivatization of glyphosate was performed with 4-chloro-3,5-dinitrobenzotrifluoride (CNBF). In pH 9.5 H(3)BO(3)-Na(2)B(4)O(7) media, the reaction of glyphosate with CNBF completed at 60 degrees C for 30min. The
Wahid Khan et al.
Drug testing and analysis, 3(6), 363-372 (2011-06-24)
Paromomycin (PM) is an aminoglycoside antibiotic, first isolated in the 1950s, and approved in 2006 for treatment of visceral leishmaniasis. Although isolated six decades back, sufficient information essential for development of pharmaceutical formulation is not available for PM. The purpose
Ingrid Freuze et al.
Journal of chromatography. A, 1175(2), 197-206 (2007-11-21)
Experimental and theoretical influence of multivalent cations on the analysis of glyphosate and aminomethyl phosphonic acid (AMPA) was studied in pure water and in one surface water. The procedure chosen, based on derivatization with FMOC-Cl, HPLC separation, and fluorescence detection

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