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Merck
CN

C9392

(±)-Coniine

≥98%, liquid

别名:

2-Propylpiperidine

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关于此项目

经验公式(希尔记法):
C8H17N
化学文摘社编号:
分子量:
127.23
UNSPSC Code:
12352200
PubChem Substance ID:
EC Number:
221-801-3
MDL number:
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InChI key

NDNUANOUGZGEPO-UHFFFAOYSA-N

InChI

1S/C8H17N/c1-2-5-8-6-3-4-7-9-8/h8-9H,2-7H2,1H3

SMILES string

CCCC1CCCCN1

assay

≥98%

form

liquid

color

, clear colorless to yellow-green

density

0.85 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Application

Coniine, a neurotoxic alkaloid from hemlock, is used in comparative analysis versus other alkaloids that act at the level of the nicotinic acid/nicotinic acetylcholine (nAChR) receptors.

Other Notes

Toxic principle of poison hemlock (racemic modification).

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

119.3 °F - closed cup

flash_point_c

48.5 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Leo J Schep et al.
Clinical toxicology (Philadelphia, Pa.), 47(8), 771-781 (2009-09-26)
A wide range of plants contain nicotinic and nicotinic-like alkaloids. Of this diverse group, those that have been reported to cause human poisoning appear to have similar mechanisms of toxicity and presenting patients therefore have comparable toxidromes. This review describes
T Blitzke et al.
Phytochemistry, 55(8), 979-982 (2001-01-05)
Phytochemical investigations of Aloe sabaea afforded a new chlorinated amide, N-4'-chlorobutylbutyramide, and the toxic piperidine alkaloids coniine, gamma-coniceine and the quarternary N,N-dimethylconiine. This is the first report of the occurrence of a chlorinated compound in the Aloeaceae family.
Versatile one-pot reductive alkylation of lactams/amides via amide activation: application to the concise syntheses of bioactive alkaloids (±)-bgugaine, (±)-coniine, (+)-preussin, and (-)-cassine.
Kai-Jiong Xiao et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(43), 12792-12796 (2010-10-13)
Patrick L West et al.
Pediatric emergency care, 25(11), 761-763 (2009-11-17)
The ingestion of poison hemlock, or Conium maculatum, is described in a 2-year-old boy. He had the onset of abdominal pain and weakness after being fed C. maculatum picked by his sister from the roadside 2 hours earlier. He had
Ingestion of poison hemlock (Conium maculatum).
B S Frank et al.
The Western journal of medicine, 163(6), 573-574 (1995-12-01)

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