D4893
3,4-脱氢-L-脯氨酸
≥98% (TLC), suitable for ligand binding assays
别名:
(S)-3-吡咯啉-2-羧酸, 3,4-二脱氢-L-脯氨酸
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关于此项目
经验公式(希尔记法):
C5H7NO2
化学文摘社编号:
分子量:
113.11
Beilstein:
5376764
EC 号:
MDL编号:
UNSPSC代码:
12352209
eCl@ss:
32160406
PubChem化学物质编号:
NACRES:
NA.26
产品名称
3,4-脱氢-L-脯氨酸,
方案
≥98% (TLC)
表单
powder
技术
ligand binding assay: suitable
颜色
white
mp
248-250 °C
应用
peptide synthesis
SMILES字符串
OC(=O)[C@H]1NCC=C1
InChI
1S/C5H7NO2/c7-5(8)4-2-1-3-6-4/h1-2,4,6H,3H2,(H,7,8)/t4-/m0/s1
InChI key
OMGHIGVFLOPEHJ-BYPYZUCNSA-N
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一般描述
3,4-脱氢-L-脯氨酸起脯氨酰-t-RNA合成酶的作用。
生化/生理作用
3,4-脱氢-L-脯氨酸用作各种酶的底物和抑制剂。 3,4-脱氢-L-脯氨酸可用于抑制延伸蛋白的生物合成。 3,4-脱氢-L-脯氨酸是氨基酸氧化酶NikD的替代底物。3,4-脱氢-L-脯氨酸抑制软骨细胞分泌胶原蛋白。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Acute respiratory failure (1985)
Chunxiang Xu et al.
BMC plant biology, 11, 38-38 (2011-02-26)
Hydroxyproline rich glycoproteins (HRGPs) are implicated to have a role in many aspects of plant growth and development but there is limited knowledge about their localization and function during somatic embryogenesis of higher plants. In this study, the localization and
Annick Méjean et al.
Biochemistry, 49(1), 103-113 (2009-12-04)
Anatoxin-a and homoanatoxin-a are two potent cyanobacterial neurotoxins. We recently reported the identification of the gene cluster responsible for the biosynthesis of these toxins in cyanobacteria and proposed a biosynthetic scheme starting from L-proline and involving three polyketide synthases for
Maïté Vicré et al.
Plant physiology, 138(2), 998-1008 (2005-05-24)
Plant roots of many species produce thousands of cells that are released daily into the rhizosphere. These cells are commonly termed border cells because of their major role in constituting a biotic boundary layer between the root surface and the
D M Goli et al.
Carbohydrate research, 259(2), 219-241 (1994-06-17)
(2R,3R,4S)-2-Hydroxymethylpyrrolidine-3,4-diol (1,4-dideoxy-1,4-imino-D-ribitol) was synthesized in five steps from N-protected (2S)-3,4-dehydroproline methyl esters. The stereoselective reaction of osmium tetraoxide with dehydroproline derivatives gave high yields of (2S,3R,4S)-3,4-dihydroxyprolines (2,3-trans-3,4-cis-3,4-dihydroxy-L-prolines) accompanied by small amounts (< 15%) of the diastereomeric (2S,3S,4R)-3,4-dihydroxyprolines (2,3-cis-3,4-cis-3,4-dihydroxy-L-prolines). The mixture
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