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Merck
CN

442446

3-氯-1-丙烯

analytical standard

别名:

烯丙基氯, 3-氯-1-丙烯, 氯丙烯

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关于此项目

线性分子式:
CH2=CHCH2Cl
化学文摘社编号:
分子量:
76.52
EC Number:
203-457-6
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
635704
MDL number:
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InChI

1S/C3H5Cl/c1-2-3-4/h2H,1,3H2

InChI key

OSDWBNJEKMUWAV-UHFFFAOYSA-N

SMILES string

ClCC=C

grade

analytical standard

vapor density

2.6 (vs air)

vapor pressure

20.58 psi ( 55 °C), 5.71 psi ( 20 °C)

expl. lim.

11.2 %

packaging

ampule of 1000 mg

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

refractive index

n20/D 1.414 (lit.)

bp

44-46 °C (lit.)

mp

−130 °C (lit.)

density

0.939 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

room temp

General description

3-Chloro-1-propene can undergo reaction with copper(I)bromide-augmented organozinc reagent in the presence of cuprous bromide to yield phosphonate.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

target_organs

Nervous system,Liver,Kidney, Respiratory system

存储类别

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-25.6 °F

flash_point_c

-32 °C

ppe

Eyeshields, Faceshields, Gloves

法规信息

危险化学品
此项目有

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Allylations of [(diethoxyphosphinyl) difluoromethyl] zinc bromide as a convenient route to 1, 1-difluoro-3-alkenephosphonates
Burton.JD and Sprague.GL
The Journal of Organic Chemistry, 54, 613-617 (1989)
Fumihiro Amemiya et al.
Organic & biomolecular chemistry, 9(11), 4256-4265 (2011-04-13)
Product selectivity control based on a liquid-liquid parallel laminar flow has been successfully demonstrated by using a microreactor. Our electrochemical microreactor system enables regioselective cross-coupling reaction of aldehyde with allylic chloride via chemoselective cathodic reduction of substrate by the combined
Y He et al.
Drug and chemical toxicology, 18(4), 315-331 (1995-11-01)
Chronic exposure to allyl chloride (ALL) is known to produce a central-peripheral distal axonopathy. In relation to the mechanism(s), the present study was conducted to examine the abilities of ALL and its putative metabolites, i.e., epichlorohydrin, glycerol alpha-monochlorohydrin, allyl alcohol
B M de Rooij et al.
Occupational and environmental medicine, 54(9), 653-661 (1998-01-10)
To evaluate the use of urinary mercapturic acids as a biomarker of human exposure to allyl chloride (3-chloropropene) (AC). During three regular shut down periods in a production factory for AC, both types of variables were measured in 136 workers
Qing-Shan Wang et al.
Neurochemical research, 30(11), 1387-1395 (2005-12-13)
To accurately know the time-dependent changes of the lipid peroxidation and antioxidative status for elucidating the mechanism of neuropathy induced by allyl chloride (AC), the malondialdehyde (MDA), anti-reactive oxygen species (anti-ROS), glutathione (GSH), catalase (CAT), glutathione peroxidase (GPx) and superoxide

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