442446
3-氯-1-丙烯
analytical standard
别名:
烯丙基氯, 3-氯-1-丙烯, 氯丙烯
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关于此项目
线性分子式:
CH2=CHCH2Cl
化学文摘社编号:
分子量:
76.52
EC Number:
203-457-6
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
635704
MDL number:
InChI
1S/C3H5Cl/c1-2-3-4/h2H,1,3H2
InChI key
OSDWBNJEKMUWAV-UHFFFAOYSA-N
SMILES string
ClCC=C
grade
analytical standard
vapor density
2.6 (vs air)
vapor pressure
20.58 psi ( 55 °C), 5.71 psi ( 20 °C)
expl. lim.
11.2 %
packaging
ampule of 1000 mg
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
refractive index
n20/D 1.414 (lit.)
bp
44-46 °C (lit.)
mp
−130 °C (lit.)
density
0.939 g/mL at 25 °C (lit.)
application(s)
cleaning products
cosmetics
environmental
food and beverages
personal care
format
neat
storage temp.
room temp
General description
3-Chloro-1-propene can undergo reaction with copper(I)bromide-augmented organozinc reagent in the presence of cuprous bromide to yield phosphonate.
Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Nervous system,Liver,Kidney, Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
-25.6 °F
flash_point_c
-32 °C
ppe
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Allylations of [(diethoxyphosphinyl) difluoromethyl] zinc bromide as a convenient route to 1, 1-difluoro-3-alkenephosphonates
Burton.JD and Sprague.GL
The Journal of Organic Chemistry, 54, 613-617 (1989)
Histopathological changes within the testis caused by allyl chloride exposure in mice.
M Zhao et al.
Bulletin of environmental contamination and toxicology, 60(3), 494-501 (1998-04-07)
Shin-ichi Ikeda et al.
Chemical communications (Cambridge, England), (4)(4), 457-459 (2006-02-24)
The Ni-catalyzed coupling of allyl chlorides and enynes has been developed; the cyclization of enynes was triggered by the addition of pi-allylnickel species to the alkyne part, followed by the incorporation of the alkene part.
B M de Rooij et al.
Drug metabolism and disposition: the biological fate of chemicals, 24(7), 765-772 (1996-07-01)
Allyl chloride (AC) is used as intermediate in the synthesis of epichlorohydrin (ECH). We investigated the biotransformation of AC in rats to select potential urinary biomarkers of exposure. For this purpose, we developed analytical methods to measure different selected urinary
Yan-Bo Yu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(46), 14643-14648 (2012-10-12)
Simply id(all)ylic: a copper- and phosphine-ligand-free Pd-catalyzed direct allylation of electron-deficient polyfluoroarenes with allylic chlorides and the reaction mechanism are described. The simple catalytic system, broad substrate scope, and excellent functional-group compatibility of this protocol provides a useful and facile
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